学歴
2010. 3. 東京理科大学理学部応用化学科 卒業
2012. 3. 東京理科大学大学院総合化学研究科修士課程 修了
2014. 3. 東京理科大学大学院総合化学研究科博士課程 修了
(2012.9-10にドイツ・ルール大学に留学)
2014. 3. 博士(理学)取得(東京理科大学)
職歴
2014 .4- 東京理科大学理学部応用化学科 助教
2018 .4- 東京理科大学理学部応用化学科 特別講師
2018.10- ジョンソンマッセイジャパン合同会社
兼務
2018 .4- 東京理科大学光触媒国際研究センター
専門
クラスター化学、ナノ物質化学、物理化学
受賞
2009. 9. 第3回分子科学討論会優秀ポスター賞
2010. 1. 第19回日本MRS学術シンポジウム奨励賞
2012. 3. 平成23年度東京理科大学学生表彰(TUS AWARD)
2013. 4. 第93回日本化学会春季年会学生講演賞
2013. 6. ナノ学会第11回大会若手優秀ポスター発表賞
2013.11. 第3回CSJ化学フェスタ2013優秀ポスター発表賞
2014. 4. 平成25年度笹川科学研究奨励賞
2015.11. 第66回コロイドおよび界面化学討論会若手口頭講演賞
2016. 1. 第25回日本MRS年次大会奨励賞
2017. 3. 宇部興産学術振興財団奨励賞
その他特記事項
2012. 3. 東京理科大学総合化学研究科首席総代
2012. 4. 東京理科大学博士課程学費半額免除者に選定
2012. 6. 日本学生支援機構奨学金(修士課程)返済全額免除者に選定
2013.10. 日本学術振興会特別研究員に内定(助教採用に伴い辞退)
2014. 3. 博士課程短期修了
2014. 6. 日本学生支援機構奨学金(博士課程)返済全額免除者に選定
競争的資金(研究費のある共同研究含)
2012. 6. 東京理科大学学生研究助成
2013. 3. 日本科学協会笹川科学研究助成
2013. 5. 加藤科学振興会研究奨励
2014. 2. 東京工業大学基金研究助成
2014. 7. 東京理科大学奨励研究助成
2014. 9. 住友電工グループ財団研究助成
2015. 6. 村田学術振興財団研究助成
2015. 6. 一樹工業技術奨励会研究助成
2015. 6. 日揮・実吉奨学会研究助成
2015. 9. マツダ財団研究助成
2016. 2. 中部電気利用基礎研究振興財団研究助成
2016. 3. 材料科学技術振興財団研究助成
2016. 4. 科学研究費補助金若手研究(B)
2016. 4. 国際科学技術財団研究助成
2017. 2. 双葉電子記念財団研究助成
2017. 3. 宇部興産学術振興財団奨励賞
2017. 4. 高橋産業経済研究財団研究助成
2017. 6 人工光合成研究センター共同研究
2018. 4. 科学研究費補助金若手研究(B)
2018. 6 人工光合成研究センター共同研究
学会委員学会
2018. 5-2020.5 ナノ学会 学会会報編集委員
学術論文
53)"Effect of Ligand on Electronic State of Gold in Ligand-Protected
Gold Clusters Elucidated by X-ray Absorption Spectroscopy"
T. Matsuyama, J. Hirayama,Y. Fujiki, S. Kikkawa, W. Kurashige, H. Asakura,
N. Kawamura, Y. Negishi, N. Nakatani, K. Hatada, F. Ota, S. Yamazoe
J. Phys. Chem. C. 125, 5, 3143-3149 (2021).
Selected as "Supplementary Cover"
52)"Mechanistic Study of Silane Alcoholysis Reaction with Self-Assembled
Monolayer-Functionalized Gold Nanoparticle Catalysts"
K. Isozaki, T. Taguchi, K. Ishibashi, T. Shimoaka, W. Kurashige, Y. Negishi,
T. Hasegawa, M. Nakamura, K. Miki
Catalysts 10, 908 (2020)..
Invited to "Special Issue"
51)"Activation of Water-Splitting Photocatalysts by Loading with Ultrafine
Rh-Cr Mixed-Oxide Cocatalyst Nanoparticles"
W. Kurashige, Y. Mori, S. Ozaki, M. Kawachi, S. Hossain, T. Kawawaki, C. J. Shearer, A. Iwase, G. F. Metha, S. Yamazoe, A. Kudo, Y. Negishi
Angew. Chem., Int. Ed., 59, 7076-7082 (2020).
Selected as "Hot Paper"
50)"Electron Microscopic Observation of an Icosahedral Au13 Core in
Au25(SePh)18 and Reversible Isomerization between Icosahedral and Face-Centered
Cubic Cores in Au144(SC2H4Ph)60"
R. Takahata, S. Yamazoe, Y. Maehara, K. Yamazaki, S. Takano, W. Kurashige, Y. Negishi, K. Gohara, T. Tsukuda
J. Phys. Chem. C, 124, 6907-6912 (2020).
Selected as "Supplementary Cover"
49)"Understanding and Designing One-Dimensional Assemblies of Ligand-Protected
Metal Nanoclusters"
S. Hossain, Y. Imai, Y. Motohashi, Z. Chen, D. Suzuki, T. Suzuki, Y. Kataoka, M. Hirata, T. Ono, W. Kurashige, T. Kawawaki, T. Yamamoto, Y. Negishi
Mater. Horizon, 7, 796-803, (2020).
Invited "Communication"
Selected as "Inside Front Cover"
Press release in "English version" and "Japanese version"
48)"γ-Alumina-Supported Pt17 Cluster: Controlled Loading, Geometrical
Structure, and Size-Specific Catalytic Activity for Carbon Monoxide and
Propylene Oxidation"
Y. Negishi, N. Shimizu, K. Funai, R. Kaneko, K. Wakamatsu, A. Harasawa, S. Hossain, M. E. Schuster, D. Ozkaya, W. Kurashige, T. Kawawaki, S. Yamazoe, S. Nagaoka
Nanoscale Adv. 2, 669-678 (2020).
Selected as "Front Cover"
47)"Atomic-Level Understanding of Effect of Heteroatom Doping of the
Cocatalyst on Water-Splitting Activity in AuPd or AuPt Alloy Cluster-Loaded
BaLa4Ti4O15"
W. Kurashige, R. Hayashi, K. Wakamatsu, Y. Kataoka, S. Hossain, A. Iwase, A. Kudo, S. Yamazoe, Y. Negishi
ACS Appl. Energy Mater., 2, 4175-4187 (2019).
Selected as "Supplementary Cover"
46)"Dynamic Behavior of Thiolate-Protected Gold–Silver 38-Atom Alloy
Clusters in Solution"
Y. Niihori, S. Hashimoto, Y. Koyama, S. Hossain, W. Kurashige, Y. Negishi
J. Phys. Chem. C, 123, 13324-13329 (2019).
Selected as "Supplementary Cover"
Press release in "English version" and "Japanese version"
Highlighted in "AZO MATERIALS"
45)"Carbon-nanotube-based Photocatalysts for Water Splitting in Cooperation
with BiVO4 and [Co(bpy)3]3+/2+"
T. Izawa, V. Kalousek, D. Miyamoto, N. Murakami, H. Miyake, T. Tajima, W. Kurashige, Y. Negishi, K. Ikeue, T. Ohkubo, Y. Takaguchi
Chem. Lett., 48, 410-413 (2019).
Selected as "Editor's Choice"
44)"Deepening the Understanding on Thiolate-Protected Metal Clusters
Using High-Performance Liquid Chromatography"
Y. Niihori, K. Yoshida, S. Hossain, W. Kurashige, Y. Negishi
Bull. Chem. Soc. Jpn, 92, 664-695 (2019)..
Invited Accunt to Special Issue"Material Innovation"
HIghlighted in "Inside Cover"
43)"Alloy Clusters: Precise Synthesis and Mixing Effects"
S. Hossain, Y. Niihori, L. V. Nair, B. Kumar, W. Kurashige, Y. Negishi
Acc. Chem. Res., 51, 3114-3124 (2018).
Invited Article to Special Issue"Toward Atomic Precision in Nanoscience"
Selected as "Supplementary Cover"
42)"Hetero-Biicosahedral [Au24Pd(PPh3)10(SC2H4Ph)5Cl2]+ Nanocluster:
Selective Synthesis and Optical and Electrochemical Properties"
L. V. Nair, S. Hossain, S. Takagi, Y. Imai, G. Hu, S. Wakayama, B. Kumar, W. Kurashige, D.-e. Jiang, Y. Negishi
Nanoscale, 10, 18969-18979 (2018).
Selected as "Back Cover"
Selected as "2018 Nanoscale Hot Article Collections"
41)"Atomic and Isomeric Separation of Thiolate-Protected Alloy Clusters"
Y. Niihori, Y. Koyama, S. Watanabe, S. Hashimoto, S. Hossain, L. V. Nair,
B. Kumar, W. Kurashige, Y. Negishi
J. Phys. Chem. Lett., 9, 4930-4934 (2018).
Selected as "Supplementary Cover"
40)"Synthesis and characterization of metal-diaminobipyridine complexes
as low-cost co-catalysts for photo-sensitized hydrogen evolution"
K. Ikeue, M. Inokuchi, M. Sakai, T. Ooyabe, T. Vagvala, V. Kalousek, W.
Kurashige, Y. Negishi, Y. Funasako
Inorganica Chim. Acta., 482, 821-829 (2018).
39)"Au25-Loaded BaLa4Ti4O15 Water-Splitting Photocatalyst with Enhanced
Activity and Durability Produced Using New Chromium Oxide Shell Formation
Method"
W. Kurashige, R. Kumazawa, D. Ishii, R. Hayashi, Y. Niihori, S. Hossain,
L. V. Nair, T. Takayama, A. Iwase, S. Yamazoe, T. Tsukuda, A. Kudo, Y.
Negishi
J. Phys. Chem. C, 122, 13669-13681 (2018).
Invited Article to "Prashant V. Kamat Festschrift"
38)"Thiolate-Protected Trimetallic Au~20Ag~4Pd and Au~20Ag~4Pt Alloy
Clusters with Controlled Chemical Composition and Metal Positions"
S. Hossain, T. Ono, M. Yoshioka, G. Hu, M. Hosoi, Z. Chen, L. V. Nair,
Y. Niihori, W. Kurashige, D.-e. Jiang, Y. Negishi
J. Phys. Chem. Lett., 9, 2590-2594 (2018).
37)"Au25 Cluster-Loaded SrTiO3 Water-Splitting Photocatalyst; Preparation
and Elucidation of The Effect of Cocatalyst Refinement on Photocatalytic
Activity"
W. Kurashige, R. Kumazawa, Y. Mori, Y. Negishi
J. Mater. Appl. 7, 1-11 (2018).
36)"High-performance Liquid Chromatography Mass Spectrometry of Gold
and Alloy Clusters Protected by Hydrophilic Thiolates"
Y. Niihori, D. Shima, K. Yoshida, K. Hamada, L. V. Nair, S. Hossain, W.
Kurashige, Y. Negishi
Nanoscale, 10, 1641-1649 (2018).
Selected as "Back Cover"
35)"Photo-induced H2 Evolution from Water via the Dissociation of
Excitons in Water-Dispersible Single-Walled Carbon Nanotube Sensitizers"
K. Ishimoto, T. Tajima, H. Miyake, M. Yamagami, W. Kurashige, Y. Negishi,
Y. Takaguchi
Chem. Commun., 54, 393-396 (2018).
34)"Incorporating a TiOx Shell in Single-Walled Carbon Nanotube/Fullerodendron
Coaxial Nanowires: Increasing the Photocatalytic Evolution of H2 from
Water under Irradiation with Visible Light"
K. Kurniawan, T. Tajima, Y. Kubo, H. Miyake, W. Kurashige, Y. Negishi and
Y. Takaguchi
RSC Adv., 7, 31617-31770 (2017).
33)"Understanding and Practical Use of Ligand and Metal Exchange Reactions
in Thiolate-Protected Metal Clusters to Synthesize Controlled Metal Clusters"
Y. Niihori, S. Hossain, S. Sharma, B. Kumar, W. Kurashige, Y. Negishi
Chem. Rec. (Personal Accounts), 17, 473-484 (2017).
Invited "Personal Accounts"
Selected as "Outside Front Cover"
32)"Monodisperse Iridium Clusters Protected by Phenylacetylene: Implication
for Size-Dependent Evolution of Binding Sites"
H. Yamamoto, P. Maity, R. Takahata, S. Yamazoe, K. Koyasu, W. Kurashige, Y. Negishi, T. Tsukuda
J. Phys. Chem. C, 121, 10936-10941 (2017).
Invited Article to "Special Issue"
31)"[Pt17(CO)12(PPh3)8]n+ (n = 1, 2): Synthesis and Geometric/Electronic
Structures"
L. V. Nair, S. Hossain, S. Wakayama, S. Takagi, M. Yoshioka, J. Maekawa,
A. Harasawa, B. Kumar, Y. Niihori, W. Kurashige, Y. Negishi
J. Phys. Chem. C, 121, 11002-11009 (2017).
Invited Article to "Special Issue"
30)"Perspective: Exchange Reactions in Thiolate-Protected Metal Clusters"
Y. Niihori, S. Hossain, B. Kumar, L. V. Nair, W. Kurashige, Y. Negishi
APL Mater. (Perspective), 5, 053201 (2017).
Invited "Perspective" to "Special Issue"
Highlighted in "Featured"
29)"SWCNT photocatalyst: Hydrogen Evolution from Water upon Photoexcitation
of (8,3)SWCNT at 680-nm Light"
N. Murakami, Y. Tango, H. Miyake, T. Tajima, Y. Nishina, W. Kurashige,
Y. Negishi, Y. Takaguchi
Sci. Rep., 7, 43445 (7 pages) (2017).
28)"Separation of Glutathionate-Protected Gold Clusters by Reversed-Phase
Ion Pair High-Performance Liquid Chromatography"
Y. Niihori, Y. Kikuchi, D. Shima, C. Uchida, S. Sharma, S. Hossain, W.
Kurashige, Y. Negishi
Ind. Eng. Chem. Res. 56, 1029-1035 (2017)
Invited Article as "A Winner of Best Presentation Award at 251th ACS Meeting"
Highlighted in "Outside Front Cover"
Highlighted in "Virtual Special Issue"
27)"Ligand Exchange Reactions in Thiolate-Protected Au25 Nanoclusters
with Selenolates or Tellurolates: Preferential Exchange Sites and Effects
on Electronic Structure"
S. Hossain, W. Kurashige, S. Wakayama, B. Kumar, L. V. Nair, Y. Niihori,
Y. Negishi
J. Phys. Chem. C, 120, 25861-25869 (2016).
26)"Tuning the Electronic Structure of Thiolate-Protected 25-Atom
Clusters by Co-Substitution with Metals Having Different Preferential Sites"
S. Sharma, S. Yamazoe, T. Ono, W. Kurashige, Y. Niihori, K. Nobusada,
T. Tsukuda, Y. Negishi
Dalton Trans. (Communications), 45, 18064-18068 (2016).
Selected as "Outside Back Cover"
25)"Halogen Adsorbates on Polymer-Stabilized Gold Clusters:Mass Spectrometric
Detection and Effects on Catalysis"
R. Ishida, S. Arii, W. Kurashige, S. Yamazoe, K. Koyasu, Y. Negishi, T.
Tsukuda
Chin. J. Catal., 37, 1656-1661 (2016).
Invited Article to "Special Issue"
24)"Improvements in the Ligand-Exchange Reactivity of Phenylethanethiolate-Protected
Au25 Nanocluster by Ag or Cu Incorporation"
Y. Niihori, M. Eguro, A. Kato, S. Sharma, B. Kumar, W. Kurashige, K. Nobusada,
Y. Negishi
J. Phys. Chem. C, 120, 14301-14309 (2016).
23)"Precise Synthesis, Functionalization and Application of Thiolate-Protected
Gold Clusters"
W. Kurashige, Y. Niihori, S. Sharma, Y. Negishi
Coord. Chem. Rev., 320-321, 238-250 (2016).
Invited "Review" to "Special Issue"
22)"High-Resolution Separation of Thiolate-Protected Gold Clusters
by Reversed-Phase High-Performance Liquid Chromatography"
Y. Niihori, C. Uchida, W. Kurashige, Y. Negishi
Phys. Chem. Chem. Phys. (Perspective), 18, 4251-4265 (2016).
Invited "Perspective"
Selected as "Outside Front Cover"
21)"Hierarchy of bond stiffnesses within icosahedral-based gold clusters
protected by thiolates"
S, Yamazoe, S. Takano, W. Kurashige, T. Yokoyama, K. Nitta, Y. Negishi,
T. Tsukuda
Nat. Commun. 7, 10414 (2016).
20)"Effect of Trimetallization in Thiolate-Protected Au24−nCunPd Clusters"
S. Sharma, W. Kurashige, K. Nobusada, Y. Negishi
Nanoscale, 7, 10616-10612 (2015).
Selected as "Back Cover"
19)"Controlled Loading of Small Aun Clusters (n = 10–39) onto BaLa4Ti4O15
Photocatalysts: Toward an Understanding of Size Effect of Co-Catalyst on
Water Splitting Photocatalytic Activity"
Y. Negishi, Y. Matsuura, R. Tomizawa, W. Kurashige, Y. Niihori, T. Takayama,
A. Iwase, A. Kudo
J. Phys. Chem. C, 119, 11214-11232 (2015).
Invited Article to "Special Issue"
18)"A Critical Size for Emergence of Nonbulk Electronic and Geometric
Structures in Dodecanethiolate-Protected Au Clusters"
Y. Negishi, T. Nakazaki, S. Malola, S. Takano, Y. Niihori, W. Kurashige,
S. Yamazoe, T. Tsukuda, H. Häkkinen
J. Am. Chem. Soc., 137, 1206-1212 (2015).
Highlighted in "Nature Nanotechnology" (HP・PDF・in Japanease)
17)"Recent Progress in the Functionalization Methods of Thiolate-Protected
Gold Clusters"
W. Kurashige, Y. Niihori, S. Sharma, Y. Negishi
J. Phys. Chem. Lett. (Perspective), 5, 4134-4142 (2014).
Selected as "Outside Front Cover"
Invited "Perspective"
Highlighted in "Editorial"
16)"The Preferential Location of Coinage Metal Dopants (M = Ag or
Cu) in [Au25-xMx(SC2H4Ph)18]- (x~1) as Determined by EXAFS and DFT Calculations"
S. Yamazoe, W. Kurashige, K. Nobusada, Y. Negishi, T. Tsukuda
J. Phys. Chem. C, 118, 25284-25290 (2014).
15)"Au25 Clusters Containing Unoxidized Tellurolates in the Ligand
Shell"
W. Kurashige, S. Yamazoe, M. Yamaguchi, K. Nishido, K. Nobusada, T. Tsukuda,
Y. Negishi
J. Phys. Chem. Lett., 5, 2072-2076 (2014).
14)"A New Synthesis Concept for Multiply Doped Gold Clusters [(M@AunM'm)Lk]a+"
A. Puls, P. Jerabek, W. Kurashige, M. Förster, M. Molon, T. Bollermann,
M. Winter, C. Gemel, Y. Negishi, G. Frenking, R. A. Fischer
Angew. Chem., Int. Ed., 53, 4327-4331 (2014).
13)"A twisted bi-icosahedral Au25 cluster enclosed by bulky arenethiolates"
J. Nishigaki, S. Yamazoe, S. Kohara, A. Fujiwara, W. Kurashige, Y. Negishi,
T. Tsukuda
Chem. Commun., 50, 839-841 (2014).
12) "Co-Sensitization Properties of Glutathione-Protected Au25 Cluster
on Ruthenium Dye Sensitized TiO2 Photoelectrode"
K. Nakata, S. Sugawara, W. Kurashige, Y. Negishi, M. Nagata, S. Uchida,
C. Terashima, T. Kondo, M. Yuasa, A. Fujishima
Int. J. Photoenergy, 2013, 456583 (7 pages) (2013).
11) "Toward the Creation of Stable, Functionalized Metal Clusters"
Y. Negishi, W. Kurashige, Y. Niihori, K. Nobusada
Phys. Chem. Chem. Phys. (Perspective), 15, 18736-18751 (2013).
Selected as "Outside Front Cover"
Invited "Perspective"
Selected as "HOT article"
10) "Formation of a Pd@Au12 Superatomic Core in Au24Pd1(SC12H25)18
Probed by 197Au Mössbauer and Pd K-edge EXAFS Spectroscopy"
Y. Negishi, W. Kurashige, Y. Kobayashi, S. Yamazoe, N. Kojima, M. Seto,
T. Tsukuda
J. Phys. Chem. Lett., 4, 3579-3583 (2013).
9) "Ag44(SeR)30: A Hollow Cage Silver Cluster with Selenolate Protection"
I. Chakraborty, W. Kurashige, K. Kanehira, L. Gell, H. Hakkinen, Y. Negishi,
T. Pradeep
J. Phys. Chem. Lett., 4, 3531-3355 (2013).
8) "Selenolate-Protected Au38 Nanoclusters: Isolation and Structural
Characterization"
W. Kurashige, S. Yamazoe, K. Kanehira, T. Tsukuda, Y. Negishi
J. Phys. Chem. Lett., 4, 3181-3185 (2013).
7) "Synthesis of Stable CunAu25-n Nanoclusters (n = 1-9) using Selenolate
Ligands"
W. Kurashige, K. Munakata, K. Nobusada, Y. Negishi
Chem. Commun., 49, 5447-5449 (2013).
Selected as "Back Cover"
6) "Remarkable Enhancement in Ligand-Exchange Reactivity of Thiolate-Protected Au25 Nanocluster by Single Pd Atom Doping"
Y. Niihori, W. Kurashige, M. Matsuzaki, Y. Negishi
Nanoscale (Communications), 5, 508-512 (2013).
Selected as "Back Cover"
蔵重 亘 【特別講師】