Total citations are 18,916 by Google Scholar and 16,099 by Scopus as of 25th November 2024.
Total impact factor is 1716.7.
2025
***)"Tunable Structural Rearrangement in Cu Cluster Assemblies through
Linker and Solvent Alterations"
S. Das, J. Sakai, R. Nakatani, A. Kondo, R. Tomioka, T. Kawawaki, S. Biswas,
Y. Negishi
ChemRvix
***)"An Atomically Precise Pt17 Nanocluster: Their Electronic Structure
and High Activity for A Hydrogen Evolution Reaction"
K. Oiwa, K. Ikeda, R. Kurosaki, K. Sato, N. Nishi, H. Tachibana, M. A. Haque, T. Kawawaki, K. Iida, Y. Negishi
ChemRvix
***)"Atomically Precise [Cu23H4(SC7H7)18(PPh3)6] Nanocluster: Structural
Integration of Johnson Solids through A Cu(0) Center and Electrocatalytic
Functionality"
S. Biswas, Y. Shingyochi, M. Kamiyama, M. Ogami, H. Song, T. Kawawaki,
D. Jiang, Y. Negishi
ChemRvix
254)"Ligand-Dependent Intracluster Interactions in Electrochemical
CO2 Reduction Using Cu14 Nanoclusters"
Y. Shingyouchi, M. Ogami, S. Biswas, T. Tanaka, M. Kamiyama, K. Ikeda, S. Hossain, Y. Yoshigoe, D. J. Osborn, G. F. Metha, T. Kawawaki, Y. Negishi
Small in press.
253)"Designed Construction of Two New Atom-precise Three-dimensional
and Two-dimensional Ag12 Cluster-assembled Materials"
R. Nakatani, J. Sakai, A. Saha, A. Kondo, R. Tomioka, T. Kawawaki, S. Das, Y. Negishi
Nanoscale in press.
Invited Article to "Metal nanoclusters"
252)"Highly Selective Methanol Synthesis Using Electrochemical CO2
Reduction with Defect-Engineered Cu58 Nanoclusters"
S. Biswas, T. Tanaka, H. Song, M. Ogami, Y. Shingyouchi, S. Hossain, M.
Kamiyama, T. Kosaka, R. Nakatani, Y. Niihori, S. Das, T. Kawawaki, D.-e.
Jiang, Y. Negishi
Small Sci. in press. (ChemRvix)
251)"Metal Single-atom Interaction with Graphitic Carbon Nitride Surface
Based on Density Functional Theory Calculations and Linear Regression Analysis"
A. T. Hanindrivo, M. Takagi, Y. Tanaka, T. Kawawaki, Y. Negishi, T. Shimazaki,
M. Tachikawa
Chem. Phys. 588, 112478 (2025).
2024
250)"Suppression of Pt Nanocluster Aggregation and Enhanced Oxygen
Reduction Activity by Heteroatom Doping of Carbon Nanotubes"
M. A. Haque, R. Kurosaki, K. Oiwa, K. Ikeda, K. Sato, N. Nishi, H. Tachibana,
T. Kawawaki, Y. Negishi
ACS Appl. Energy Mater. 7, 10137-1-325 (2024).
Selected as "Supplementary Cover"
249)"Atomically Precise Au24Pt(thiolate)12(dithiolate)3 Nanoclusters
with Excellent Electrocatalytic Hydrogen Evolution Reactivity"
M. Sera, S. Hossain, S. Yoshikawa, K. Takemae, A. Ikeda, T. Tanaka, T.
Kosaka, Y. Niihori, T. Kawawaki, Y. Negishi
J. Am. Chem. Soc. 146, 29684-29693 (2024). (ChemRvix)
Press release in "English version" and "Japanese version"
Highlighted in "Nikkei Shinbun"and "Nikkan Kogyou Shinbun"
248)"Silver Cluster-assembled Material as Matrix for Enzyme Immobilization
Towards Highly Efficient Biocatalyst"
J. Sakai, K. Sasaki, R. Nakatani, S. Das, Y. Negishi
Nanoscale. in press.
Invited Article to "themed collection: Nanocatalysis"
Selected as "Front Cover"
247)"Simultaneous Ionic Cobalt Sensing and Toxic Congo Red Dye Removal:
A Circular Economic Approval Involving Silver Enhanced Fluorescence"
M. Sahua, M. Ganguly, P. Sharma, A. Doi, Y. Negishi
Nanoscale Adv. in press.
246)"Ultrafine Rhodium–Chromium Mixed-Oxide Cocatalyst with Facet-Selective
Loading for Excellent Photocatalytic Water Splitting"
D. Hirayama, T. Kawawaki, S. Oguchi, M. Ogano, N. Kon, T. Yasuda, A. Higami,
Y. Negishi
J. Am. Chem. Soc. 146, 26808-26818 (2024).
Press release in "English version" and "Japanese version"
Highlighted in "Nikkei Shinbun" and "Nikkan Kogyou Shinbun"
245)"Metal-Organic Frameworks as Promising Electrocatalysts for Nitrogen
Reduction Reaction: Mapping the Research Landscape and Identifying Future
Trends"
R. Nakatani, S. Das, Y. Negishi
J. Mater. Chem. A 12, 26350-26366 (2024).
Highlighted in "Themed collection: Journal of Materials Chemistry A Recent Review Articles"
Selected as "Back Cover"
244)"Navigating Challenges and Possibilities for Improving Polymer
Electrolyte Membrane Fuel Cells via Pt Electrocatalyst, Support and Ionomer
Advancements"
M. A. Haque, T. Kawawaki, Y. Negishi
Int. J. Hydrog. Energy, 85, 30-47 (2024).
243)"Controlled Aggregation of Pt/PtH/Rh/RhH doped Silver Superatomic Nanoclusters into 16-electron Supermolecules"
T.-H. Chiu, M. Pillay, Y.-Y. Wu, Y. Niihori, Y. Negishi, J.-Y. Chen, Y.-J.
Chen, S. Kahlal, J.-Y. Saillard, C.-W. Liu
Chem. Sci..15, 14660-14667 (2024).
242)"Precise Synthesis of Ligand-Protected Metal Nanoclusters for Electrochemical/Photoelectrochemical Applications"
T. Kawawaki, Y. Negishi
Chem. Lett. 53, upae155 (2024).
Invited "Award Highlight Review".
241)"Luminescent Hydride-Free [Cu7(SC5H9)7(PPh3)3] Nanocluster: Facilitating
Highly Selective C-C Bond Formation"
S. Biswas, A. Pal, M. K. Jena, S. Hossain, J. Sakai, S. Das, B. Sahoo,
B. Pathak, Y. Negishi
J. Am. Chem. Soc. 146, 20937-20944 (2024)
Highlighted in "ChemistryViews".
240)"Advancing Electrochemical CO2 Reduction with Group 11 Metal Nanoclusters
for Renewable Energy Solutions"
S. Biswas, Y. Shingyouchi, M. Ogami, M. Kamiyama, T. Kawawaki, Y. Negishi
EcoEnergy 2, 400-418 (2024).
Invited Review
239)"Highly Selective Separation of Benzene/Cyclohexane by Three-Dimensional
Covalent Organic Framework with 8,8-Connected bcu Net Topology"
Y. Zhao, T. Irie, D. Wen, H. Mabuchi, K. Sasaki, M. Nozaki, R. Tomioka,
W. Zhu, S. Das, T. Ben, Y. Negishi
ACS Mater. Lett. 6, 3063-3070 (2024). (ChemRxiv.)
238)"Triplet-Mediator Ligand-Protected Metal Nanocluster Sensitizers for Photon Upconversion"
D. Arima, S. Hidaka, S. Yokomori, Y. Niihori, Y. Negishi, R. Oyaizu, T.
Yoshinami, K. Kobayashi, M. Mitsui
J. Am. Chem. Soc. 146, 16630-16638 (2024).
Selected as "Supprementary Cover"
237)"Silver Cluster Assembled Materials: A Model-Driven Perspective
on Recent Progress, with a Spotlight on Ag12 Cluster Assembly"
S. Biswas, Y. Negishi
Chem. Rec. 24, e202400052 (2024).
Selected as "Outside Front Cover"
236)"Exploring the Impact of Various Reducing Agents on Cu Nanocluster
Synthesis"
S. Biswas, Y. Negishi
Dalton Trans. 53, 9657-9663 (2024).
Invited "Frontier article" (Invited by Sally Howells-Wyllie, Editor, Dalton Transactions)
Selected as "Outside Front Cover"
Selected as "Dalton Transactions HOT Articles"
235)"Structure and Application Portfolio of Intricately Architected
Silver Cluster-Assembled Materials"
R. Nakatani, S. Das, Y. Negishi
Nanoscale 16, 9642-9658 (2024).
Invited "Review" (Invited by Edward Gardner, Development Editor)
Selected as "Outside Back Cover"
Highlighted in "Themed collection: Recent Review Articles"
234)"Triplet-Triplet Annihilation-Based Photon Upconversion Using
Nanoparticles and Nanoclusters"
Y. Niihori, T, Kosaka, Y. Negishi
Mater. Horiz. 11, 2304-2322 (2024)
Selected as "Inside Front Cover"
Highligted in "Themed Collection: Recent Review Articles"
233)"Size-Dependent Carbon Dioxide Reduction Activity of Copper Nanoparticle
and Nanocluster Electrocatalysts"
T. Kawawaki, T. Okada, K. Takemae, S. Tomihari, Y. Negishi
ChemNanoMat 10, e202300575 (2024).
Invited Review to Special Collection "Early Career Researchers 2023"
(Invited by Dr. Claire M. Cobley, Editor-in-Chief)
Selected as "Hot Topic: Carbon Dioxide"
232)"Tiara-Like Hexanuclear Nickel-Platinum Alloy Nanocluster"
T. Okada, T. Kawawaki, K. Takemae, S. Tomihari, T. Kosaka, Y. Niihori,
Y. Negishi
J. Phys. Chem. Lett. 15, 1539–1545 (2024).
Selected as "Supplementary Cover"
231)"Three-Dimensional Covalent Organic Framework with “the” Topology"
S. Das, H. Mabuchi, T. Irie, K. Sasaki, M. Nozaki, R. Tomioka, D. Wen,
Y. Zhao, T. Ben, Y. Negishi
Small 20, 2307666 (2024). (ChemRxiv.)
Selected as "Back Cover"
230)"A Comprehensive Analysis of Luminescent Crystalized Cu Nanoclusters"
S. Biswas, Y. Negishi
J. Phys. Chem. Lett. 15, 947-958 (2024)
Invited Perspective (Invited by Prof. Gregory Scholes, Editor-in-Chief)
Selected as "Supplementary Cover"
229)"Covalent Organic Frameworks: Cutting-Edge Materials for Carbon
Dioxide Capture and Water Harvesting from Air"
H. Mabuchi, T. Irie, J. Sakai, S. Das, Y. Negishi
Chem. Euro. J. 30, e202303474 (2024).
Invited Review to special collection "Covalent Organic Frameworks:
Green Synthesis and Cutting-Edge Applications"
Selected as "Inside Front Cover"
Selected as "Hot Topic: Carbon Dioxide"
228)"Unlocking the Potential of Atom-Precise Ag12 Cluster Assembled
Material as Highly Efficient SERS Sensor for Detection of Hg2+ Ion"
R. Nakatani, S. Biswas, T. Irie, Y. Niihori, S. Das, Y. Negishi
ACS Mater. Lett. 6, 438-445 (2024).
Selected as "Supplementary Cover"
227)"Atomically Precise Metal Nanoclusters as Catalysts for Electrocatalytic
CO2 Reduction"
T. Kawawaki, T. Okada, D. Hirayama, Y. Negishi
Green Chem. 26, 122-163 (2024).
Invited Review to "Advances in Electrosynthesis for a Greener Chemical Industry"
Selected as "Outside Back Cover"
226)"Metal Nanoclusters as a Superior Polysulfides Immobilizer Towards Highly
Stable Lithium-Sulfur Batteries"
K. Sun, Y. Fu, T. Sekine, H. Mabuchi, S. Hossain, Z. Qiang, D. Liu, S.
Das, D. He, Y. Negishi
Small 20, 2304210 (2024).
Selected as "Back Cover"
Press release in "English version" and "Japanese version"
Highlighted in "Nikkei Shinbun", "Nikkankogtyo Shinbun" and "Yahoo! News"
2023
225)"Clarifying the Electronic Structure of Anion-templated Silver
Nanoclusters by Optical Absorption Spectroscopy and Theoretical Calculation"
Y. Horita, S. Hossain, M. Ishimi, P. Zhao, M. Sera, T. Kawawaki, S. Takano, Y. Niihori, T. Nakamura, T. Tsukuda, M. Ehara, Y. Negishi
J. Am. Chem. Soc. 145, 23533-23540 (2023).
224)"Advances in Cu Nanocluster Catalyst Design: Recent Progress and
Promising Applications"
S. Biswas, S. Das, Y. Negishi
Nanoscale Horiz. 8, 1509-1522 (2023).
Selected as "Inside Front Cover"
Selected as "Nanoscale Horizons Most Popular 2023 Articles"
Selected as "Nanoscale Horizons HOT Papers"
Selected as "Themed collection Nanoscale Horizons Highly Cited Articles"
223)"Nanoporous 3D Covalent Organic Frameworks with pts Topology as
Anticancer Drug Nanocarriers"
Y. Zhao, T. Irie, J. Sakai, T. Sekine, H. Mabuchi, S. Biswas, S. Das,
T. Ben, Y. Negishi
ACS Appl. Nano Mater. 6, 19210-19217 (2023). (ChemRxiv)
Selected as "Supplementary Cover"
222)"A New Two-dimensional Luminescent Ag12 Cluster-assembled Material
and Its Catalytic Activity for Reduction of Hexacyanoferrate (III)"
R. Nakatani, S. Biswas, T. Irie, J. Sakai, D. Hirayama, T. Kawawaki, Y.
Niihori, S. Das, Y. Negishi
Nanoscale 15, 16299-16306 (2023)..
Selected as "Outside Back Cover"
221)"Elucidation of the Electronic Structures of Thiolate-Protected Gold Nanoclusters
by Electrochemical Measurements"
T. Kawawaki, Y. Negishi
Dalton Trans. 52, 15152-15167 (2023).
Invited Review to "The New Talent: Asia-Pacific themed issue" (Invited by Associate editor, Prof. Takashi Uemura)
Selected as "Inside Front Cover"
Selected as "Dalton Transactions HOT Articles"
Selected as "2023 Frontier and Perspective articles"
220)"Synthesis and Luminescence Properties of Two Silver Cluster-Assembled
Materials for Selective Fe3+ Sensing"
J. Sakai, S. Biswas, T. Irie, H. Mabuchi, T. Sekine, Y. Niihori, S. Das,
Y. Negishi
Nanoscale 15, 12227-12234 (2023).
Selected as "Outside Front Cover"
Press release in "English version" and "Japanese version"
Highlighted in "Nikkei Shinbun" and "Yomiuri Shinbun"
219)"Nested Keplerian Architecture of [Cu58H20(SPr)36(PPh3)8]2+ Nanocluster"
S. Biswas, S. Hossian, T. Kosaka, J. Sakai, D. Arima, Y. Niihori, M. Mitsui,
D.-e. Jiang, S. Das, S. Wang, Y. Negishi
Chem. Commun. 59, 9336-9339 (2023).
Selected as "Outside Front Cover"
218)"Counteranion-induced Structural Isomerization of Phosphine-protected PdAu8 and PtAu8 Clusters"
Y. Fujiki, T. Matsuyama, S. Kikkawa, J. Hirayama, H. Takaya, N. Nakatani,
N. Yasuda, K. Nitta, Y. Negishi, S. Yamazoe
Commun. Chem. 6, 129 (2023).
Invited Article to "Special Issue"
Press release in "Japanese version"
217)"Five Novel Silver-Based Coordination Polymers as Photoluminescent
Sensing Platforms for the Detection of Nitrobenzene"
T. Sekine, J. Sakai, Y. Horita, H. Mabuchi, T. Irie, S. Hossain, T. Kawawaki,
S. Das, S. Takahashi, S. Das, Y. Negishi
Chem. Euro. J. 29, e202300706 (2023)..
Selected as "Inside Cover"
216)"Activation of Hydrogen-Evolution Reactivity in an Rh-doped SrTiO3
Photocatalyst under Visible-Light Irradiation by Loading with Controlled
Platinum Nanoclusters"
D. Yazaki, T. Kawawaki, T. Tanaka, D. Hirayama, Y. Shingyouchi, Y. Negishi
Energy Adv. 2, 1148-1154 (2023).
Invited Article (Invited by Editor-in-Chief, Prof. Volker Presser)
Selected as "Outside Back Cover"
Selected as "Blue and Green Hydrogen Production & Storage"
Selected as "Energy Advances: Highlight Japan & South Korea"
215)"Progress and Prospects in the Design of Functional Atomically-precise Ag(I)-thiolate Nanoclusters and Their Assembly Approaches"
S. Biswas, S. Das, Y. Negishi
Coord. Chem. Rev. 492, 215255 (2023).
214)"Metal Single-Atom Cocatalyst on Carbon Nitride for the Photocatalytic
Hydrogen Evolution Reaction: Effects of Metal Species"
Y. Akinaga, T. Kawawaki, H. Kameko, Y. Yamazaki, K. Yamazaki, Y. Nakayasu,
K. Kato, Y. Tanaka, A. T. Hanindriyo, M. Takagi, T. Shimazaki, M. Tachikawa,
A. Yamakata, Y. Negishi
Adv. Funct. Mater. 33, 2303321 (2023)
Selected as "Back Cover"
Selected as "Hot Topic: Carbon, Graphite, and Graphene"
Selected as "Hot Topic: Photocatalysis"
Selected as "Hot Topic: Water Splitting"
213)"Carbon Nitride Loaded with an Ultrafine, Monodisperse, Metallic
Platinum-Cluster Cocatalyst for the Photocatalytic Hydrogen-Evolution Reaction"
D. Yazaki, T. Kawawaki, D. Hirayama, M. Kawachi, K. Kato, S. Oguchi, Y.
Yamaguchi, S. Kikkawa, Y. Ueki, S. Hossain, D. J. Osborn, F. Ozaki, S.
Tanaka, J. Yoshinobu, G. F. Metha, S. Yamazoe, A. Kudo, A. Yamakata, Y.
Negishi
Small, 19, 2208287 (2023).
Selected as "Front Cover"
Selected as "Hot Topic: Photocatalysts"
212)"Anion-templated Silver Nanoclusters: Precise Synthesis and Geometric
Structure"
Y. Horita, M. Ishimi, Y. Negishi
Sci. Technol. Adv. Mater. 24, 2203832 (2023).
Invited Review to "Special Issue"
211)"Pt17 Nanocluster Electrocatalysts: Preparation and Origin of
High Oxygen Reduction Reaction Activity"
T. Kawawaki, Y. Mitomi, N. Nishi, R. Kurosaki, K. Oiwa, T. Tanaka, H.
Hirase, S. Miyajima, Y. Niihori, D. J. Osborn, T. Koitaya, G. F Metha,
T. Yokoyama, K. Iida, Y. Negishi
Nanoscale,15, 7272 (2023).
Selected as "Outiside Front Cover"
Press release in "English version" and "Japanese version"
Highlighted in several medias (1/2/3)
Selected as "Nanoscale Most Popular 2023 Articles"
210)"Vertex-Shared Linear Superatomic Molecules: Stepping Stones to
Novel Materials Composed of Noble Metal Clusters"
Y. Niihori, S. Miyajima, A. Ikeda, T. Kosaka, Y. Negishi
Small Sci. 3, 2370009 (2023).
Invited Review (Invited by Editor, Dr. Sneha Rhode)
Selected as "Outiside Front Cover"
209)"Key Factors for Connecting Silver-based Icosahedral Superatoms
by Vertex Sharing"
S. Miyajima, S. Hossain, A. Ikeda, T. Kosaka, T. Kawawaki, Y. Niihori,
T. Iwasa, T. Taketsugu, Y. Negishi
Commun. Chem. 6, 57, (2023). (Research Square)
Invited Article to "Special Issue"
Press release in "English version" and "Japanese version"
Highlighted in "Nikkan Kogyo Shinbun"
208)"Silver Cluster-Assembled Materials for Label-Free DNA Detection"
S. Das, T. Sekine, H. Mabuchi, S. Hossain, S. Das, S. Aoki, S. Takahashi,
Y. Negishi
Chem. Commun. 59, 4000-4003, (2023).
Invited Paper (Invited by Executive Editor, Dr. Richard Kelly)
Selected as "Outiside Front Cover"
207)"Reduction and Diffusion of Cr2O3 Layer into P25 Particles upon
High-Temperature Annealing in Comparison with BaLa4Ti4O15 and Al:SrTiO3"
A. S. Alotabi, Y. Yin, D. J. Osborn, T. D. Small, S. Ozaki, Y. Kataoka,
Y. Negishi, K. Domen, G. F. Metha, G. G. Andersson
ACS Appl. Mater. Interfaces, 15, 14990-15003, (2023)
206)"Improved Activity for the Oxygen Evolution Reaction using a Tiara-like
Thiolate-protected Nickel Nanocluster"
S. Funaki, T. Kawawaki, T. Okada, K. Takemae, S. Hossain, Y. Niihori,
T. Naitoh, M. Takagi, T. Shimazaki, S. Kikkawa, S. Yamazoe, Tachikawa,
Y. Negishi
Nanoscale, 15, 5201-5208 (2023).
Selected as "Outiside Back Cover"
205)"Rapid Virus Detection using Magnetic Second Harmonics of Superparamagnetic
Iron Oxide Nanoparticles"
R. Hirota, T. Murayama, R. Katsumi, T. Kawawaki, S. Yabukami, R. Igarashi,
Y. Negishi, M. Kusakabe, M. Sekino, T. Yatsui, A. Kuwahata
AIP Adv. 13, 025144 (2023).
204)"Record Ultralarge-Pores, Low Density Three-Dimensional Covalent
Organic Framework for Controlled Drug Delivery"
Y. Zhao, S. Das, T. Sekine, H. Mabuchi, T. Irie, J. Sakai, D. Wen, W.
Zhu, T. Ben, Y. Negishi
Angew. Chem. Int. Ed. 62, e202300172 (2023). (ChemRxiv)
Selected as "Hot Topic: Drug Delivery"
Selected as "Hot Topic: Mesoporous Materials"
Press release in "English version" and "Japanese version"
Highlighted in "Nikkei Tech Foresign"
203)"Redox-Guided Synthesis of Au-V2O5-MnO2 Nanoflower Composites
with Enhanced Electrical Conductance for Supercapacitor Applications"
S. Rudra, S. Das, P. Maji, A. Nayak, Y. Negishi, M. Pradhan, U. Nandi
ACS Appl. Nano Mater. 6, 1648-1659 (2023).
202)"Promoting Photocatalytic Carbon-Dioxide Reduction by Tuning the
Properties of Cocatalysts"
T. Kawawaki, Y. Akinaga, D. Yazaki, H. Kameko, D. Hirayama, Y. Negishi
Chem. Euro. J. 29, e202203387 (2023).
Invited "Review" to special collection "Photocatalysis for a Brighter Future"
Selected as "Inside Cover"
Selected as "Chemistry Europe Reviews"
Selected as "Editors' Choice: Spotlights"
Selected as "Hot Topic: Carbon Dioxide"
Selected as "Hot Topic: Photocatalysts"
Selected as "Review Showcase"
Highlighted in "Frontispiece"
Selected as "Tpo Downloaded Article"
201)"Atomically Precise Thiolate-Protected Gold Nanoclusters: Current
Status of Designability of the Structure and Physicochemical Properties"
S. Hossain, D. Hirayama, A. Ikeda, M. Ishimi, S. Funaki, A. Samanta, T.
Kawawaki, Y. Negishi
Aggregate, 4, e255 (2023).
Invited Review (Invited by Editor-in-Chief, Prof. Ben Zhong Tang)
Selected as "Inside Front Cover"
2022
200)"Precise Control over Pore Hydrophilicity in Covalent Organic
Framework Membranes for High-Flux Separation of Dyes from Water"
Z. Li, S. Das, T. Sekine, H. Mabuchi, R. Kaneko, J. Sakai,T. Irie, E.
Kamio, T. Yoshioka, J. Suo, Q. Fang, T. Kawawaki, H. Matsuyama, Y. Negishi
ACS Appl. Nano Mater. 5, 17632-17639 (2022)
Selected as "Supplementary Cover"
199)"Three-Dimensional Covalent Organic Frameworks with scu-c Topology
for Drug Delivery"
S. Das, T. Sekine, H. Mabuchi, T. Irie, J. Sakai, Y. Zhao, Q. Fang, Y.
Negishi
ACS Appl. Mater. Interfaces. 14, 48045-48051 (2022). (ChemRxiv)
Press release in "English version" and "Japanese version"
Highlighted in "JST Science Portal" and others (1/2/3/4/5/6)
198)"Composition Control of Alloy Nanoparticles Consisting of Bulk-Immiscible
Au and Rh Metals via an Ionic Liquid/Metal Sputtering Technique for Improving
Their Electrocatalytic Activity"
K. Akiyoshi, Y. Watanabe, T. Kameyama, T. Kawawaki Y. Negishi, S. Kuwabata,
T. Torimoto
Phys. Chem. Chem. Phys. 24, 24335-24344 (2022).
197)"Galvanic Replacement Reaction and Kirkendall Effect in Room Temperature
Synthesis of Tubular NiSe2: A Nanozyme Catalyst with Peroxidase-Like Activity"
S. Sarkar, Y. Negishi, T. Pal
Dalton Trans. 51, 12904-12914 (2022).
Invited Article
196)"Ligand Effect on the CO Oxidation Activity of CeO2 Supported
Gold Nanocluster Catalysts"
V. Truttmann, H. Drexler, M. Stöger-Pollach, T. Kawawaki, Y. Negishi,
N. Barrabés, G. Rupprechter
ChemCatChem, 14, e202200322 (2022).
Selected as "Editors' Choice: Spotlights"
Selected as "Cover Feature"
195)"Virus Detection using Second Harmonics of Magnetic Nanoparticles"
R. Hirota, T. Murayama, R. Katsumi, T. Kawawaki, S. Yabukami, R. Igarashi,
Y. Negishi, M. Kusakabe, M. Sekino, T. Yatsui, A. Kuwahata
IEEJ Trans. Elect. Electron. Eng., 17, 1228-1230 (2022)..
194)"Selective Formation of [Au23(SPhtBu)17]0, [Au26Pd(SPhtBu)20]0
and [Au24Pt(SC2H4Ph)7(SPhtBu)11]0 by Controlling Ligand-exchange Reaction"
Y. Negishi, H. Horihata, A. Ebina, S. Miyajima, M. Nakamoto, A. Ikeda,
T. Kawawaki, S. Hossain
Chem. Sci., 13, 5546-5556 (2022).
Selected as "Back Cover"
193)"Suppression of Phosphine-Protected Au9 Clusters Agglomeration
on SrTiO3 Particles Using a Chromium Hydroxide Layer"
A. S. Alotabi, D. J. Osborn, S. Ozaki, Y. Kataoka, Y. Negishi, S. Tesana,
G. F. Metha, G. G. Andersson
Mater. Adv. 3, 3620-3630 (2022).
192)"Metal-nanocluster Science and Technology: My Personal History
and Outlook"
Y. Negishi
Phys. Chem. Chem. Phys, 24, 7569-7594 (2022).
Invited "Perspective"
Selected as "Outside Front Cover"
Selected as "2022 HOT Article"
191)"Ion-Selective Covalent Organic Framework Membrane as a Catalytic
Polysulfide Trap to Arrest Redox Shuttle Effect in Lithium–Sulfur Batteries"
K. Sun, C. Wang, Y. Dong, P. Guo, P. Cheng, Y. Fu, D. Liu, D. He, S. Das,
Y Negishi
ACS Appl. Mater. Interfaces, 14, 4079-4090 (2022).
190)"Development and Functionalization of Visible-light-driven Water-splitting
Photocatalysts"
T. Kawawaki, M. Kawachi, D. Yazaki, Y. Akinaga, D. Hirayama, Y. Negishi
Nanomaterials, 12, 344 (2022).
Invited Review to Special Issue "Advanced Nanomaterials for Water Splitting"
Selected as "Feature Paper"
Highlighted in "Nanomaterials MDPI Twitter"
2021
189)"Supported, ~1-nm-Sized Platinum Clusters: Controlled Preparation
and Enhanced Catalytic Activity"
T. Kawawaki, N. Shimizu, Y. Mitomi, D. Yazaki, S. Hossain, Y. Negishi
Bull. Chem. Soc. Jpn, 94, 2853-2870 (2021).
Invited Accunt to Special Issue "Masterpiece Materials with Functional Excellence"
Highlighted in "Inside Cover"(Twittter 1/2)
Highlighted in "Account/Review Collection 2020-2021"
188)"Creation of High-Performance Heterogeneous Photocatalysts by
Controlling Ligand Desorption and Particle Size of Gold Nanocluster"
T. Kawawaki, Y. Kataoka, M. Hirata, Y. Akinaga, R. Takahata, K. Wakamatsu,
Y. Fujiki, M. Kataoka, S. Kikkawa, A. S. Alotabi, S. Hossain, D. J. Osborn,
T. Teranishi, G. G. Andersson, G. F. Metha, S. Yamazoe, Y. Negishi
Angew. Chem. Int. Ed. 60, 21340-21350 (2021).
Selected as "Inside Cover"
Selected as "Hot Topic: Photocatalysts"
Selected as "Hot Topic: Water Splitting"
Press release in "English version" and "Japanese version"
Highlighted in "Nikkan Kogyo Shinbun"
187)"Simple and High-Yield Preparation of Carbon-Black-Supported ~1-nm
Platinum Nanoclusters and Their Oxygen Reduction Reactivity"
T. Kawawaki, N. Shimizu, K. Funai, Y. Mitomi, S. Hossain, S. Kikkawa, D.
J. Osborn, S. Yamazoe, G. F. Metha, Y. Negishi
Nanoscale 13, 14679-14687 (2021).
Selected as "Back Cover"
Selected as "Nanoscale 2022 Lunar New Year Collection"
Highlighted in "Nanoscale & Nanoscale Advances Blog", "Nanoscale Twitter", and "Nanoscale Facebook"
186)"Thermal Stability of Crown-motif [Au9(PPh3)8]3+ and [MAu9(PPh3)8]2+
(M = Pd, Pt) Clusters: Effects of Gas Composition, Single-atom Doping,
and Counter Anions"
T. Matsuyama, S. Kikkawa, Y. Fujiki, M. Tsukada, H. Takaya, N. Yasuda,
K. Nitta, N. Nakatani, Y. Negishi, S. Yamazoe
J. Chem. Phys.155, 044307 (2021).
Invited Article to "Special Issue"
185)"[Ag23Pd2(PPh3)10Cl7]0: A New Family of Synthesizable Bi-icosahedral
Superatomic Molecules"
S. Hossain, S. Miyajima, T. Iwasa, R. Kaneko, T. Sekine, A. Ikeda, T. Kawawaki,
T. Taketsugu, Y. Negishi
J. Chem. Phys. 155, 024302 (2021).
Invited Article to "Special Issue"
184)"Thiolate-Protected Metal Nanoclusters: Recent Development in
Synthesis, Understanding of Reaction, and Application in Energy and Environmental
Field"
T. Kawawaki, A. Ebina, Y. Hosokawa, S. Ozaki, D. Suzuki, S. Hossain, Y.
Negishi
Small 17, 202005328 (2021).
Invited Review to "Special Issue"
Selected as"Frontispiece"
Selected as "Hot Topic: Water Splitting"
183)"Toward the Creation of High-performance Heterogeneous Catalysts
by Controlled Ligand Desorption from Atomically Precise Metal Nanoclusters"
T. Kawawaki, Y. Kataoka, M. Hirata, Y. Iwamatsu, S. Hossain, Y. Negishi
Nanoscale Horiz. 6, 409-448 (2021).
Invited "Review"
Selected as "Outside Front Cover"
Selected as "Nanoscale 2022 Lunar New Year Collection"
Selected as "Nanoscale Most Popular 2021 Articles"
Selected as "Nanoscale Horizons, Nanoscale, and ChemComm: Nanocatalysis"
Top 10% of highly cited articles from the Royal Society of Chemistry
182)"Cu(II)-Based Nanofibrous Metallogel for Phenoxazinone Synthase-Like
Activity"
S. Sarkar, P. K. Maji, Y. Negishi, S. Dutta, T. N. Das, R. Pan, S. Sarkar
ACS Appl. Nano Mater. 4, 1455-1466 (2021).
181)"Effect of Ligand on Electronic State of Gold in Ligand-Protected
Gold Clusters Elucidated by X-ray Absorption Spectroscopy"
T. Matsuyama, J. Hirayama,Y. Fujiki, S. Kikkawa, W. Kurashige, H. Asakura,
N. Kawamura, Y. Negishi, N. Nakatani, K. Hatada, F. Ota, S. Yamazoe
J. Phys. Chem. C. 125, 5, 3143-3149 (2021).
Selected as "Supplementary Cover"
180)"Creation of Active Water-splitting Photocatalysts by Controlling
Cocatalysts Using Atomically Precise Metal Nanoclusters"
T. Kawawaki,Y. Kataoka, S. Ozaki, M. Kawachi, M. Hirata, Y. Negishi
Chem. Commun. 57, 417-440 (2021).
Invited "Feature Article"
Selected as "Inside Front Cover"
Selected as "highly cited reviews in nanoscience research from ChemComm"
2020
179)"Atomically Precise Alloy Nanoclusters"
T. Kawawaki, Y. Imai, D. Suzuki, S. Kato, I. Kobayashi, T. Suzuki, R. Kaneko, S. Hossain, Y. Negishi
Chem. Euro. J. 26, 16150-16193 (2020).
Invited "Review"
Selected as "Front Cover" and "Cover Profile"
Selected as "Hot Topic: Gold"
Highlighted in "Frontispiece"
178)"Cell Density-Dependent Accumulation of Low Polarity Gold Nanocluster
in Cultured Vascular Endothelial Cells"
T. Hara, M. Saeki, Y. Negishi, T. Kaji, C. Yamamoto
J. Toxicol. 45, 795-800.
177)"Increase in CO2 Reduction Rate via Optical Near-Field Effect"
T. Yatsui, Y. Nakamura, Y. Suzuki, T. Morimoto, Y. Kato, M. Yamamoto,
T. Yoshida, W. Kurashige, N. Shimizu, Y. Negishi, K. Iida, K. Nobusada
J. Nonophotonics 14, 046011 (2020).
176)"Determining and Controlling Cu-Substitution Sites in Thiolate-Protected Gold-Based 25-Atom Alloy Nanoclusters"
S. Hossain, D. Suzuki, T. Iwasa, R. Kaneko, T. Suzuki, S. Miyajima, Y.
Iwamatsu, S. Pollitt, T. Kawawaki, N. Barrabés, G. Rupprechter, Y. Negishi
J. Phys. Chem. C 124, 22304-22313 (2020).
Invited to "Special Issue"
Selected as "Supplementary Cover"
175)"Controlled Colloidal Metal Nanoparticles and Nanoclusters: Recent
Applications as Cocatalysts for Improving Photocatalytic Water-splitting
Activity"
T. Kawawaki, Y. Mori, K. Wakamatsu, S. Ozaki, M. Kawachi, S. Hossain, Y.
Negishi
J. Mater. Chem. A 8, 16081-16113 (2020)..
Invited "Review"
Top 5% of highly cited works from Japanese institutions
174)"Mechanistic Study of Silane Alcoholysis Reaction with Self-Assembled
Monolayer-Functionalized Gold Nanoparticle Catalysts"
K. Isozaki, T. Taguchi, K. Ishibashi, T. Shimoaka, W. Kurashige, Y. Negishi, T. Hasegawa, M. Nakamura, K. Miki
Catalysts 10, 908 (2020)..
Invited to "Special Issue"
173)"One-, Two-, and Three-Dimensional Self-Assembly of Atomically
Precise Metal Nanoclusters"
A. Ebina, S. Hossain, H. Horihata, S. Ozaki, S. Kato, T. Kawawaki, Y. Negishi
Nanomaterials, 10, 1105, (2020).
Invited Review to "Special Issue"
172)"Gold Nanoclusters as Electrocatalysts: Size, Ligands, Heteroatom
doping, and Charge Dependences"
B. Kumar, T. Kawawaki, N. Shimizu, Y. Imai, D. Suzuki, S. Hossain, L.
V. Nair, Y. Negishi
Nanoscale, 12, 9969-9979 (2020).
Selected as "Outside Front Cover"
Selected as "Nanoscale Most Popular Articles"
Selected as "Nanoscale Lunar New Year Collection 2021"
Top 5% of highly cited works from Japanese institutions
171)"Activation of Water-Splitting Photocatalysts by Loading with
Ultrafine Rh-Cr Mixed-Oxide Cocatalyst Nanoparticles"
W. Kurashige, Y. Mori, S. Ozaki, M. Kawachi, S. Hossain, T. Kawawaki,
C. J. Shearer, A. Iwase, G. F. Metha, S. Yamazoe, A. Kudo, Y. Negishi
Angew. Chem., Int. Ed., 59, 7076-7082 (2020).
Selected as "Hot Paper"
170)"Atomic-level Separation of Thiolate-protected Metal Clusters"
Y. Negishi, S. Hashimoto, A. Ebina, K. Hamada, S. Hossain, T. Kawawaki
Nanoscale, 12, 8017-8039 (2020).
Invited "Review"
Selected as "Inside Front Cover"
169)"Electron Microscopic Observation of an Icosahedral Au13 Core
in Au25(SePh)18 and Reversible Isomerization between Icosahedral and Face-Centered
Cubic Cores in Au144(SC2H4Ph)60"
R. Takahata, S. Yamazoe, Y. Maehara, K. Yamazaki, S. Takano, W. Kurashige,
Y. Negishi, K. Gohara, T. Tsukuda
J. Phys. Chem. C, 124, 6907-6912 (2020).
Selected as "Supplementary Cover"
168)"Understanding and Designing One-Dimensional Assemblies of Ligand-Protected
Metal Nanoclusters"
S. Hossain, Y. Imai, Y. Motohashi, Z. Chen, D. Suzuki, T. Suzuki, Y. Kataoka,
M. Hirata, T. Ono, W. Kurashige, T. Kawawaki, T. Yamamoto, Y. Negishi
Mater. Horizon, 7, 796-803, (2020).
Invited "Communication"
Selected as "Inside Front Cover"
Press release in "English version" and "Japanese version"
Several examples of pick up of this work (1/2/3/4/5/6/7/8/9)
167)"γ-Alumina-Supported Pt17 Cluster: Controlled Loading, Geometrical
Structure, and Size-Specific Catalytic Activity for Carbon Monoxide and
Propylene Oxidation"
Y. Negishi, N. Shimizu, K. Funai, R. Kaneko, K. Wakamatsu, A. Harasawa,
S. Hossain, M. E. Schuster, D. Ozkaya, W. Kurashige, T. Kawawaki, S. Yamazoe,
S. Nagaoka
Nanoscale Adv. 2, 669-678 (2020).
Selected as "Front Cover"
166)"Gold Nanoclusters as Electrocatalysts for Energy Conversion"
T. Kawawaki, Y. Negishi
Nanomaterials, 10, 238 (2020).
Invited Review to "Special Issue"
165)"Photo/electrocatalysis and Photosensitization Using Metal Nanoclusters
for Green Energy and Medical Applications"
T. Kawawaki, Y. Negishi, H. Kawasaki
Nanoscale Adv. 2, 17-36 (2020).
Invited "Review"
Selected as "Inside FrontCover"
Selected as a part of "Themed Collection: Photocatalysis and Photoelectrochemistry"
Selected as "Editor's Choice: Single-atom and nanocluster catalysis"
Top 5% of highly cited works from Japanese institutions
164)"Vibrational Spectra of Thiolate Protected Gold Nanocluster with
Infrared Reflection Absorption Spectroscopy: Size and Temperature Dependent
Ordering Behavior of Organic-Monolayer"
T. Yokoyama, N. Hirata, H. Tsunoyama, T. Eguchi, Y. Negishi, A. Nakajima
J. Phys. Chem. C. 124, 363-371 (2020).
2019
163)"Elucidating Ligand Effects in Thiolate-Protected Metal Clusters
Using Au24Pt(TBBT)18 as A Model Cluster"
S. Hossain, Y. Imai, D. Suzuki, W. Choi, Z. Chen, T. Suzuki, M. Yoshioka,
T. Kawawaki, D. Lee, Y. Negishi
Nanoscale, 11, 22089-22098 (2019).
162)"Precise Synthesis of Platinum and Alloy Clusters and Elucidation
of Their Structures"
S. Hossain, Y. Imai, Y. Negishi
AIP Conf. Proc., 2186, 030018 (2019).
161)"Atomic-Level Understanding of Effect of Heteroatom Doping of
the Cocatalyst on Water-Splitting Activity in AuPd or AuPt Alloy Cluster-Loaded
BaLa4Ti4O15"
W. Kurashige, R. Hayashi, K. Wakamatsu, Y. Kataoka, S. Hossain, A. Iwase,
A. Kudo, S. Yamazoe, Y. Negishi
ACS Appl. Energy Mater., 2, 4175-4187 (2019).
Selected as "Supplementary Cover"
160)"Dynamic Behavior of Thiolate-Protected Gold–Silver 38-Atom Alloy
Clusters in Solution"
Y. Niihori, S. Hashimoto, Y. Koyama, S. Hossain, W. Kurashige, Y. Negishi
J. Phys. Chem. C, 123, 13324-13329 (2019).
Selected as "Supplementary Cover"
Press release in "English version" and "Japanese version"
Several examples of pick up of this work (1/2/3/4/5/6/7/8/9/10/11/12/13/14/15)
159)"Carbon-nanotube-based Photocatalysts for Water Splitting in Cooperation
with BiVO4 and [Co(bpy)3]3+/2+"
T. Izawa, V. Kalousek, D. Miyamoto, N. Murakami, H. Miyake, T. Tajima,
W. Kurashige, Y. Negishi, K. Ikeue, T. Ohkubo, Y. Takaguchi
Chem. Lett., 48, 410-413 (2019).
Selected as "Editor's Choice"
158)"Deepening the Understanding on Thiolate-Protected Metal Clusters
Using High-Performance Liquid Chromatography"
Y. Niihori, K. Yoshida, S. Hossain, W. Kurashige, Y. Negishi
Bull. Chem. Soc. Jpn, 92, 664-695 (2019)..
Invited Accunt to Special Issue"Material Innovation"
HIghlighted in "Inside Cover"
HIghlighted in "Account/Review Collection 2019-20"
2018
157)"Alloy Clusters: Precise Synthesis and Mixing Effects"
S. Hossain, Y. Niihori, L. V. Nair, B. Kumar, W. Kurashige, Y. Negishi
Acc. Chem. Res., 51, 3114-3124 (2018).
Invited Article to Special Issue"Toward Atomic Precision in Nanoscience"
Selected as "Supplementary Cover"
156)"Hetero-Biicosahedral [Au24Pd(PPh3)10(SC2H4Ph)5Cl2]+ Nanocluster:
Selective Synthesis and Optical and Electrochemical Properties"
L. V. Nair, S. Hossain, S. Takagi, Y. Imai, G. Hu, S. Wakayama, B. Kumar,
W. Kurashige, D.-e. Jiang, Y. Negishi
Nanoscale, 10, 18969-18979 (2018).
Selected as "Back Cover"
Selected as "2018 Nanoscale Hot Article Collections"
155)"Atomic and Isomeric Separation of Thiolate-Protected Alloy Clusters"
Y. Niihori, Y. Koyama, S. Watanabe, S. Hashimoto, S. Hossain, L. V. Nair,
B. Kumar, W. Kurashige, Y. Negishi
J. Phys. Chem. Lett., 9, 4930-4934 (2018).
Selected as "Supplementary Cover"
154)"Synthesis and Characterization of Metal-Diaminobipyridine Complexes
as Low-Cost Co-catalysts for Photo-Sensitized Hydrogen Evolution"
K. Ikeue, M. Inokuchi, M. Sakai, T. Ooyabe, T. Vagvala, V. Kalousek, W.
Kurashige, Y. Negishi, Y. Funasako
Inorganica Chim. Acta., 482, 821-829 (2018).
153)"An Au25(SR)18 Cluster with a Face-Centered Cubic Core"
T. Omoda, S.Takano, S. Yamazoe, K. Koyasu, Y. Negishi, T. Tsukuda
J. Phys. Chem. C, 122, 13199-13204 (2018).
152)"Au25-Loaded BaLa4Ti4O15 Water-Splitting Photocatalyst with Enhanced
Activity and Durability Produced Using New Chromium Oxide Shell Formation
Method"
W. Kurashige, R. Kumazawa, D. Ishii, R. Hayashi, Y. Niihori, S. Hossain,
L. V. Nair, T. Takayama, A. Iwase, S. Yamazoe, T. Tsukuda, A. Kudo, Y.
Negishi
J. Phys. Chem. C, 122, 13669-13681 (2018).
Invited Article to "Prashant V. Kamat Festschrift"
151)"Characterization of Floating-gate Memory Device with Thiolate-Protected
Gold and Gold-Palladium Nanoclusters"
T. Yokoyama, N. Hirata, H. Tsunoyama, Y. Negishi, A. Nakajima
AIP Adv., 8, 065002 (2018).
150)"Thiolate-Protected Trimetallic Au~20Ag~4Pd and Au~20Ag~4Pt Alloy
Clusters with Controlled Chemical Composition and Metal Positions"
S. Hossain, T. Ono, M. Yoshioka, G. Hu, M. Hosoi, Z. Chen, L. V. Nair,
Y. Niihori, W. Kurashige, D.-e. Jiang, Y. Negishi
J. Phys. Chem. Lett., 9, 2590-2594 (2018).
149)"Evolution of Silver Mediated Enhanced Fluorescent Au-Ag Nanocluster
under UVActivation: A Platform for Sensing"
J. Jana, P. Acharyya, Y. Negishi, T. Pal
ACS Omega, 3, 3463-3470 (2018).
148)"High-performance Liquid Chromatography Mass Spectrometry of Gold
and Alloy Clusters Protected by Hydrophilic Thiolates"
Y. Niihori, D. Shima, K. Yoshida, K. Hamada, L. V. Nair, S. Hossain, W.
Kurashige, Y. Negishi
Nanoscale, 10, 1641-1649 (2018).
Selected as "Back Cover"
147)"Photo-induced H2 Evolution from Water via the Dissociation of
Excitons in Water-Dispersible Single-Walled Carbon Nanotube Sensitizers"
K. Ishimoto, T. Tajima, H. Miyake, M. Yamagami, W. Kurashige, Y. Negishi,
Y. Takaguchi
Chem. Commun., 54, 393-396 (2018).
146) "Au25 Cluster-Loaded SrTiO3 Water-Splitting Photocatalyst; Preparation
and Elucidation of The Effect of Cocatalyst Refinement on Photocatalytic
Activity"
W. Kurashige, R. Kumazawa, Y. Mori, Y. Negishi
J. Mater. Appl., 7, 1−11(2018).
2017
145)"Solvent Polarity Dependent Behavior of Aliphatic Thiols and Amines
towards Intriguingly Fluorescent AuAgGSH Assembly"
J. Jana, T. Aditya, Y. Negishi, T. Pal
ACS Omega., 2, 8086-8098 (2017).
144)"Advance Aqueous Asymmetric Supercapacitor; Based on Large 2D
NiCo2O4 Nanostructures and rGO@Fe3O4 Composite"
R. Sahoo, P. Acharyya, N. K. Singh, A. Pal, Y. Negishi, T. Pal
ACS Omega., 2, 6576-6585 (2017).
143)"Incorporating a TiOx Shell in Single-Walled Carbon Nanotube/Fullerodendron
Coaxial Nanowires: Increasing the Photocatalytic Evolution of H2 from
Water under Irradiation with Visible Light"
K. Kurniawan, T. Tajima, Y. Kubo, H. Miyake, W. Kurashige, Y. Negishi and
Y. Takaguchi
RSC Adv., 7, 31617-31770 (2017).
142)"Understanding and Practical Use of Ligand and Metal Exchange
Reactions in Thiolate-Protected Metal Clusters to Synthesize Controlled
Metal Clusters"
Y. Niihori, S. Hossain, S. Sharma, B. Kumar, W. Kurashige, Y. Negishi
Chem. Rec. (Personal Accounts), 17, 473-484 (2017).
Invited "Personal Accounts"
Selected as "Outside Front Cover"
416)"Monodisperse Iridium Clusters Protected by Phenylacetylene: Implication
for Size-Dependent Evolution of Binding Sites"
H. Yamamoto, P. Maity, R. Takahata, S. Yamazoe, K. Koyasu, W. Kurashige,
Y. Negishi, T. Tsukuda
J. Phys. Chem. C, 121, 10936-10941 (2017).
Invited Article to "Special Issue"
140)"[Pt17(CO)12(PPh3)8]n+ (n = 1, 2): Synthesis and Geometric and
Electronic Structures"
L. V. Nair, S. Hossain, S. Wakayama, S. Takagi, M. Yoshioka, J. Maekawa,
A. Harasawa, B. Kumar, Y. Niihori, W. Kurashige, Y. Negishi
J. Phys. Chem. C, 121, 11002-11009 (2017)
Invited Article to "Special Issue"
139)"Fabrication and Characterization of Floating Memory Devices Based
on Thiolate-Protected Gold Nanoclusters"
N. Hirata, M. Sato, E. Tsunemi, Y. Watanabe, H. Tsunoyama, M. Nakaya,
T. Eguchi, Y. Negishi, A. Nakajima
J. Phys. Chem. C, 121, 10638-10644 (2017).
Invited Article to "Special Issue"
138)"Perspective: Exchange Reactions in Thiolate-Protected Metal Clusters"
Y. Niihori, S. Hossain, B. Kumar, L. V. Nair, W. Kurashige, Y. Negishi
APL Mater. (Perspective), 5, 053201 (2017).
Invited "Perspective" to "Special Issue"
Highlighted in "Featured"
137)"Facile Synthesis of Unique Hexagonal Nanoplates of Zn/Co Hydroxy
Sulfate for Efficient Electrocatalytic Oxygen Evolution Reaction"
S. Dutta, C. Ray, Y. Negishi, T. Pal
ACS Appl. Mater. Interfaces, 9, 8134-8141 (2017).
136)"SWCNT photocatalyst: Hydrogen Evolution from Water upon Photoexcitation
of (8,3)SWCNT at 680-nm Light"
N. Murakami, Y. Tango, H. Miyake, T. Tajima, Y. Nishina, W. Kurashige,
Y. Negishi, Y. Takaguchi
Sci. Rep., 7, 43445 (7 pages) (2017).
Introduced in "Nikkan Kogyo Shinbun"
135)"Separation of Glutathionate-Protected Gold Clusters by Reversed-Phase
Ion Pair High-Performance Liquid Chromatography"
Y. Niihori, Y. Kikuchi, D. Shima, C. Uchida, S. Sharma, S. Hossain, W.
Kurashige, Y. Negishi
Ind. Eng. Chem. Res. 56, 1029-1035 (2017)
Invited Article as "A Winner of Best Presentation Award at 251th ACS Meeting"
Highlighted in "Outside Front Cover"
Highlighted in "Virtual Special Issue"
2016
134)"Ligand Exchange Reactions in Thiolate-Protected Au25 Nanoclusters
with Selenolates or Tellurolates: Preferential Exchange Sites and Effects
on Electronic Structure"
S. Hossain, W. Kurashige, S. Wakayama, B. Kumar, L. V. Nair, Y. Niihori,
Y. Negishi
J. Phys. Chem. C, 120, 25861-25869 (2016).
133)"Tuning the Electronic Structure of Thiolate-Protected 25-Atom
Clusters by Co-Substitution with Metals Having Different Preferential Sites"
S. Sharma, S. Yamazoe, T. Ono, W. Kurashige, Y. Niihori, K. Nobusada,
T. Tsukuda, Y. Negishi
Dalton Trans. (Communications), 45, 18064-18068 (2016).
Selected as "Back Cover"
132)"Halogen Adsorbates on Polymer-Stabilized Gold Clusters: Mass
Spectrometric Detection and Effects on Catalysis"
R. Ishida, S. Arii, W. Kurashige, S. Yamazoe, K. Koyasu, Y. Negishi, T.
Tsukuda
Chin. J. Catal., 37, 1656-1661 (2016).
Invited Article to "Special Issue"
131)"Improvements in the Ligand-Exchange Reactivity of Phenylethanethiolate-Protected
Au25 Nanocluster by Ag or Cu Incorporation"
Y. Niihori, M. Eguro, A. Kato, S. Sharma, B. Kumar, W. Kurashige, K. Nobusada,
Y. Negishi
J. Phys. Chem. C, 120, 14301-14309 (2016).
130)"Precise Synthesis, Functionalization and Application of Thiolate-Protected
Gold Clusters"
W. Kurashige, Y. Niihori, S. Sharma, Y. Negishi
Coord. Chem. Rev., 320-321, 238-250 (2016).
Invited "Review" to "Special Issue"
129)"Fabrication of Nitrogen-Doped Mesoporous Carbon Coated Palladium
Nanoparticles: An Intriguing Electrocatalyst for Methanol and Formic Acid
Oxidation"
C. Ray, S. Dutta, R. Sahoo, A. Roy, Y. Negishi, T. Pal
Chem. Asian J. 11, 1588-1596 (2016).
128)"A New Stable Pd-Mn3O4 Nanocomposite as Efficient Electrocatalyst
for The Hydrogen Evolution Reaction"
C. Ray, S. Dutta, Negishi, T. Pal
Chem. Commun. 52, 6095-6098 (2016).
127)"Fabrication of Dog-Bone Shaped Au NRcore-Pt/Pdshell Trimetallic
Nanoparticles Decorated Reduced Graphene Oxide Nanosheets for Excellent
Electrocatalysis"
S. Dutta, C. Ray, A. K. Sasmal, Y. Negishi, T. Pal
J. Mater. Chem. A, 4, 3765-3776 (2016).
126)"Hierarchical Growth of ZnFe2O4 for Sensing Applications"
R. Sahoo, S. Santra, C. Ray, A. Pal, Y. Negishi, S. K. Ray, T. Pal
New. J. Chem., 40, 1861-1871 (2016).
125)"High-Resolution Separation of Thiolate-Protected Gold Clusters
by Reversed-Phase High-Performance Liquid Chromatography"
Y. Niihori, C. Uchida, W. Kurashige, Y. Negishi
Phys. Chem. Chem. Phys. (Perspective), 18, 4251-4265 (2016).
Invited "Perspective"
Selected as "Outside Front Cover"
124)"Hierarchy of bond stiffnesses within icosahedral-based gold clusters
protected by thiolates"
S, Yamazoe, S. Takano, W. Kurashige, T. Yokoyama, K. Nitta, Y. Negishi,
T. Tsukuda
Nat. Commun. 7, 10414 (2016).
Introduced in "Nikkan Kogyo Shinbun"
123)"One pot synthesis of intriguing fluorescent carbon dots for sensing
and live cell imaging"
J. Janaa, M. Gangulyb, B. Dasc, S. Dharac, Y. Negishid, T. Pal
Talanta, 150, 253-264 (2016).
2015
122)"A Unified Framework for Understanding the Structure and Modifications
of Atomically Precise Monolayer Protected Gold Clusters"
G. Natarajan, A. Mathew, Y. Negishi, R. L. Whetten, T. Pradeep
J. Phys. Chem. C, 119, 27768-27785 (2015).
121)"A Gel-Based Approach to Design Hierarchical CuS Decorated Reduced
Graphene Oxide Nanosheets for Enhanced Peroxidase-like Activity Leading
to Colorimetric Detection of Dopamine"
S. Dutta, C. Ray, S. Mallick, S. Sarkar, R. Sahoo, Y. Negishi, T. Pal
J. Phys. Chem. C, 119, 23790-23800 (2015).
120)"Understanding Ligand-Exchange Reactions on Thiolate-Protected
Gold Cluster by Probing Isomer Distributions Using Reversed-Phase High-Performance
Liquid Chromatography"
Y. Niihori, Y. Kikuchi, A. Kato, M. Matsuzaki, Y. Negishi
ACS Nano, 9, 9347-9356 (2015).
Highlighted in "IN NANO" (HP・PDF)
119)"Preformed ZnS Nanoflower Prompted Evolution of CuS/ZnS p-n Heterojunction
for Exceptional Visible Light Driven Photocatalytic Activity"
C. Mondal, A. Singh, R. Sahoo, A. K. Sasmal, Y. Negishi, T. Pal
New. J. Chem. 39, 5628-5635 (2015).
118)"Redox Mediated Synthesis of Fe3O4-MnO2 Nanocomposite for Dye
Adsorption and Pseudocapacitance"
R. Sahoo1, M. Pradhan1, A. Roy, S. Dutta, C. Ray, Y. Negishi, A. Pal,
T. Pal
Chem. Asian J. 10, 1571-1580 (2015).
117)"Effect of Trimetallization in Thiolate-Protected Au24−nCunPd
Clusters"
S. Sharma, W. Kurashige, K. Nobusada, Y. Negishi
Nanoscale, 7, 10606-10612 (2015).
Selected as "Back Cover"
116)"Controlled Loading of Small Aun Clusters (n = 10–39) onto BaLa4Ti4O15
Photocatalysts: Toward an Understanding of Size Effect of Co-Catalyst on
Water Splitting Photocatalytic Activity"
Y. Negishi, Y. Matsuura, R. Tomizawa, W. Kurashige, Y. Niihori, T. Takayama,
A. Iwase, A. Kudo
J. Phys. Chem. C, 119, 11224-11232 (2015).
Invited Article to "Special Issue"
115)"Evolution of Tubular Copper Sulfide Nanostructures from Copper(I)-Metal
Organic Precursor: A Superior Platform for the Removal of Hg (II) and Pb
(II) Ions"
C. Ray, S. Sarkar, S. Dutta, A. Roy, R. Sahoo, Y. Negishi, T. Pal
RSC Adv., 5, 12446-12453 (2015).
114)"A Critical Size for Emergence of Nonbulk Electronic and Geometric
Structures in Dodecanethiolate-Protected Au Clusters"
Y. Negishi, T. Nakazaki, S. Malola, S. Takano, Y. Niihori, W. Kurashige,
S. Yamazoe, T. Tsukuda, H. Häkkinen
J. Am. Chem. Soc., 137, 1206-1212 (2015).
Highlighted in "Nature Nanotechnology" (HP・PDF・in Japanease)
113)"Precursor Salt Assisted Syntheses of High-Index Faceted Concave
Hexagon and Nanorod like Polyoxometalates"
J. Pal, M. Ganguly, C. Mondal, Y. Negishi, T. Pal
Nanoscale, 7, 708-719 (2015).
112)"Biomolecule-Mediated CdS-TiO2-Reduced Graphene Oxide Ternary
Nanocomposites for Efficient Visible Light Driven Photocatalysis"
S. Dutta, R. Sahoo, C. Ray, S. Sarkar, J. Jana, Y. Negishi, T. Pal
Dalton Trans., 44, 193-201 (2015).
2014
111)"Recent Progress in the Functionalization Methods of Thiolate-Protected
Gold Clusters"
W. Kurashige, Y. Niihori, S. Sharma, Y. Negishi
J. Phys. Chem. Lett. (Perspective), 5, 4134-4142 (2014).
Invited "Perspective"
Selected as "Outside Front Cover"
Highlighted in "Editorial"
110)"The Preferential Location of Coinage Metal Dopants (M = Ag or
Cu) in [Au25-xMx(SC2H4Ph)18]- (x~1) as Determined by EXAFS and DFT Calculations"
S. Yamazoe, W. Kurashige, K. Nobusada, Y. Negishi, T. Tsukuda
J. Phys. Chem. C, 118, 25284-25290 (2014).
109)"Air-Processed Inverted Organic Solar Cells Utilizing a 2-Aminoethanol-Stabilized
ZnO Nanoparticle Electron Transport Layer That Requires No Thermal Annealing"
Il Jeon, J. W. Ryan, T. Nakazaki, K. S. Yeo, Y. Negishi, Y. Matsuo
J. Mater. Chem. A, 2, 18754-18760 (2014).
Selected as "Back Cover"
108)"Account of Nitroarene Reduction with Size and Facet Controlled
CuO-MnO2 Nanocomposites"
J. Pal, C. Mondal, M. Ganguly, A. Sasmal, Y. Negishi, T. Pal
ACS Appl. Mater. Interface, 6, 9173-9184 (2014).
107)"Decoration of Fe3O4 Base Material with Pd Loaded CdS Nanoparticle
for Superior Photocatalytic Efficiencyl"
R. Sahoo, A. Roy, C. Ray, C. Mondal, Y. Negishi, S. M. Yusuf, A. Pal,
T. Pal
J. Phys. Chem. C, 118, 11485-11494 (2014).
106)"Fluorescent Au(I)@Ag2/Ag3 Giant Cluster for Selective Sensing
of Mercury(II) Ion"
M. Ganguly, C. Mondal, J. Pal, A. Pal, Y. Negishi, T. Pal
Dalton Trans., 43, 11557-11565 (2014).
105)"Advanced Use of High-Performance Liquid Chromatography for Synthesis
of Controlled Metal Clusters"
Y. Niihori, M. Matsuzaki, C. Uchida, Y. Negishi
Nanoscale, 6, 7889-7896 (2014).
Selected as "Back Cover"
104)"Au25 Clusters Containing Unoxidized Tellurolates in the Ligand
Shell"
W. Kurashige, S. Yamazoe, M. Yamaguchi, K. Nishido, K. Nobusada, T. Tsukuda,
Y. Negishi
J. Phys. Chem. Lett., 5, 2072-2076 (2014).
103)"Deposition of Zinc Oxide Nanoflowers on Different Substrates
as a Thin Film for Useful Applications"
C. Mondal, A. K. Sinha, M. Ganguly, J. Pal, S. Dhara, Y. Negishi, T. Pal
CrystEngComm, 16, 4322-4328 (2014).
102)"A Novel Concept for the Synthesis of Multiply Doped Gold Clusters
[(M@AunM'm)Lk]a+"
A. Puls, P. Jerabek, W. Kurashige, M. Förster, M. Molon, T. Bollermann,
M. Winter, C. Gemel, Y. Negishi, G. Frenking, R. A. Fischer
Angew. Chem., Int. Ed., 53, 4327-4331 (2014).
101)"Towards the Creation of Functionalized Metal Nanoclusters and
Highly Active Photocatalytic Materials Using Thiolate-Protected Magic Gold
Clusters"
Y. Negishi
Bull. Chem. Soc. Jpn (Award Accounts), 87, 375-389 (2014).
Invited "Accounts" as "a Winner of CSJ Award for Young Chemists"
Highlighted in "Back Cover"
100)"Hierarchical Au-CuO Nanocomposite from Redox Transformation Reaction
for Surface Enhanced Raman Scattering and Clock Reaction"
J. Pal, M. Ganguly, S. Dutta, C. Mondal, Y. Negishi, T. Pal
CrystEngComm, 16, 883-893 (2014).
99)"A twisted bi-icosahedral Au25 cluster enclosed by bulky arenethiolates"
J. Nishigaki, S. Yamazoe, S. Kohara, A. Fujiwara, W. Kurashige, Y. Negishi,
T. Tsukuda
Chem. Commun., 50, 839-841 (2014).
2013
98)"Crystal Plane Dependent Etching of Cuprous Oxide Nanoparticles
of Varied Shapes and Their Application in Visible Light Photocatalysis"
J. Pal, M. Ganguly, C. Mondal, A. Roy, Y. Negishi, T.Pal
J. Phys. Chem. C, 117, 24640-24653 (2013).
97)"Co-Sensitization Properties of Glutathione-Protected Au25 Cluster
on Ruthenium Dye Sensitized TiO2 Photoelectrode"
K. Nakata, S. Sugawara, W. Kurashige, Y. Negishi, M. Nagata, S. Uchida,
C. Terashima, T. Kondo, M. Yuasa, A. Fujishima
Int. J. Photoenergy, 2013, 456583 (7 pages) (2013).
96)"Toward the Creation of Stable, Functionalized Metal Clusters"
Y. Negishi, W. Kurashige, Y. Niihori, K. Nobusada
Phys. Chem. Chem. Phys. (Perspective), 15, 18736-18751 (2013).
Invited "Perspective"
Selected as "Outside Front Cover"
Selected as "HOT article"
95)"Formation of a Pd@Au12 Superatomic Core in Au24Pd1(SC12H25)18
Probed by 197Au Mössbauer and Pd K-edge EXAFS Spectroscopy"
Y. Negishi, W. Kurashige, Y. Kobayashi, S. Yamazoe, N. Kojima, M. Seto, T. Tsukuda
J. Phys. Chem. Lett., 4, 3579-3583 (2013).
94)"Ag44(SeR)30: A Hollow Cage Silver Cluster with Selenolate Protection"
I. Chakraborty, W. Kurashige, K. Kanehira, L. Gell, H. Hakkinen, Y. Negishi,
T. Pradeep
J. Phys. Chem. Lett., 4, 3531-3355 (2013).
93)"Silver Nanoparticles Decorated Reduced Graphene Oxide (rGO) Nanosheet:A
Platform for SERS Based Low-level Detection of Uranyl Ion"
S. Dutta, C. Ray, S. Sarkar, M. Pradhan,Y. Negishi, T. Pal
ACS Appl. Mater. Interface, 5, 8724-8732 (2013).
92)"Selenolate-Protected Au38 Nanoclusters: Isolation and Structural
Characterization"
W. Kurashige, S. Yamazoe, K. Kanehira, T. Tsukuda, Y. Negishi
J. Phys. Chem. Lett., 4, 3181-3185 (2013).
91)"Green Synthesis and Reversible Dispersion of Giant Fluorescent
Cluster in Solid and Liquid Phase"
M. Ganguly, J. Pal, S. Das, C. Mondal, A. Pal, Y. Negishi, T. Pal
Langmuir, 29, 10945-10958 (2013).
90)"Enhanced Photocatalytic Water Splitting by BaLa4Ti4O15 Loaded
with ~1nm Gold Nanoclusters using Glutathione-Protected Au25 Clusters"
Y. Negishi, M. Mizuno, M. Hirayama, M. Omatoi, T. Takayama, A. Iwase, A.
Kudo
Nanoscale (communications), 5, 7188-7192 (2013).
Selected as "Back Cover"
94)"Synthesis of Stable CunAu25-n Nanoclusters (n = 1-9) using Selenolate
Ligands"
W. Kurashige, K. Munakata, K. Nobusada, Y. Negishi
Chem. Commun., 49, 5447-5449 (2013).
Selected as "Back Cover"
88)"Structural Evolution of Glutathione-Protected Gold Clusters Studied
by Means of 197Au Mossbauer Spectroscopy"
N. Kojima, Y. Kobayashi, Y. Negishi, M. Seto, T. Tsukuda
Hyperfine Interact, 217, 91-98 (2013).
87)"Separation of Precise Compositions of Noble Metal Clusters Protected
with Mixed Ligands"
Y. Niihori, M. Matsuzaki, T. Pradeep, Y. Negishi
J. Am. Chem. Soc.(communications), 135, 4946-4949 (2013).
86)"Size and Structure Dependence of Electronic States in Thiolate-Protected
Gold Nanoclusters of Au25(SR)18, Au38(SR)24, and Au144(SR)60"
T. Ohta, M. Shibuta, H. Tsunoyama, Y. Negishi, T. Eguchi, A. Nakajima
J. Phys. Chem. C, 117, 3674-3679 (2013).
85)"Synthesis of High Fluorescent Silver Clusters on Au(I) Surface"
M. Ganguly, A. Pal, Y. Negishi, T. Pal
Langmuir, 29, 2033-2043 (2013).
84)"Remarkable Enhancement in Ligand-Exchange Reactivity of Thiolate-Protected
Au25 Nanocluster by Single Pd Atom Doping"
Y. Niihori, W. Kurashige, M. Matsuzaki, Y. Negishi
Nanoscale (communications), 5, 508-512 (2013).
Selected as "Back Cover"
2012
83)"Diiminic Schiff Bases: An Intriguing Class for Copper Nanoparticle
Induced Fluorescence Study"
M. Ganguly, A. Pal, Y. Negishi, T. Pal
Chem.-Eur. J., 18, 15845-15855 (2012).
82)"Ligand-Induced Stability of Gold Nanoclusters: Thiolate versus
Selenolate"
W. Kurashige, M. Yamaguchi, K. Nobusada, Y. Negishi
J. Phys. Chem. Lett., 3, 2649-2652 (2012).
81)"A New Binding Motif of Sterically Demanding Thiolates on A Gold
Cluster"
J. Nishigaki, R. Tsunoyama, H. Tsunoyama, N. Ichikuni, S. Yamazoe, Y. Negishi,
M. Ito, T. Matsuo, K. Tamao, and T. Tsukuda
J. Am. Chem. Soc.(communications), 134, 14295-14297 (2012).
80)"Effect of Copper Doping on Electronic Structure, Geometric Structure, and
Stability of Thiolate-Protected Au25 Nanoclusters"
Y. Negishi, K. Munakata, W. Ohgake, K. Nobusada
J. Phys. Chem. Lett. 3, 2209-2214 (2012).
79)"Photoresponsive Au25 Nanocluster Protected by Azobenzene Derivative
Thiolates"
Y. Negishi, U. Kamimura, M. Ide, M. Hirayama
Nanoscale, 4, 4263-4268 (2012).
Invited Article to Special Issue"
Selected as "Back Cover"
78)"Remarkable Enhancement in Aerobic Alcohol Oxidation Catalysis
of Au25 Clusters by Single Pd Atom Doping"
S. Xie, H. Tsunoyama, W. Kurashige, Y. Negishi, T. Tsukuda
ACS Catalysis (Letters), 2, 1519-1523 (2012).
77)"Synthesis and the Origin of the Stability of Thiolate-Protected
Au130 and Au187 Clusters"
Y. Negishi, C. Sakamoto, T. Ohyama, T. Tsukuda
J. Phys. Chem. Lett., 3, 1624-1628 (2012).
76)"Synthesis, Stability, and Photoluminescence Property of PdAu10(PPh3)8Cl2
Cluster"
W. Kurashige, Y. Negishi
J. Cluster Science, 23, 365-374 (2012).
75)"Study of The Structure and Electronic State of Thiolate-Protected
Gold Clusters by Means of 197Au Mossbauer Spectroscopy"
N. Kojima, K. Ikeda, Y. Kobayashi, T. Tsukuda, Y. Negishi, G. Harada,
T. Sugawara, M. Seto
Hyperfine Interact, 207, 127-131 (2012).
74)"Palladium Doping of Magic Gold Cluster Au38(SC2H4Ph)24: Formation
of Pd2Au36(SC2H4Ph)24 with Higher Stability than Au38(SC2H4Ph)24"
Y. Negishi, K. Igarashi, K. Munakata, W. Ohgake, K. Nobusada
Chem. Commun., 48, 660-662 (2012).
Selected as "Back Cover"
2011
73)"Reanalysis of 197 Au Mossbauer Spectrum of Au25(SR)18"
T. Tsukuda, Y. Negishi, Y. Kobayashi, N. Kojima
Chem. Lett., 40, 1292-1293 (2011).
72)"Fabrication and Functionalization of CuO for Tuning Superhydrophobic
Thin Film and Cotton Wool"
M. Basu, A. K. Sinha, M. Pradhan, S. Sarkar,Y. Negishi, T. Pal
J. Phys. Chem. C, 115, 20953-20963 (2011).
71)"Isolation and Structural Characterization of Octaneselenolate-Protected
Au25 Cluster"
Y. Negishi, W. Kurashige, U. Kamimura
Langmuir (Letters), 27, 12289-12292 (2011).
70)"Redox Switchable Superhydrophobic Silver Composite"
A. K. Sinha, M. Basu, M. Pradhan, S. Sarkar, Y. Negishi, T. Pal
Langmuir, 27, 11629-11635 (2011).
69)"Photoluminescence Dynamics of Organic Molecule-Passivated Si Nanoclusters"
M. Imamura, J. Nakamura, S. Fujimasa, H. Yasuda, H. Kobayashi, Y. Negishi
Eur. Phys. J. D, 63, 289-292 (2011).
68)"Isolation and Structural Characterization of Magic Silver Clusters
Protected by 4-(tert-butyl)benzyl Mercaptan"
Y. Negishi, R. Arai, Y. Niihori, T. Tsukuda
Chem Commun., 47, 5693-5695 (2011)
Selected as "Back Cover"
67)"Redox Transmetallation of Prickly Nickel Nanowires for Morphology
Controlled Hierarchical Synthesis of Nickel/Gold Nanostructures for Enhanced
Catalytic Activity and SERS Responsive Functional Material"
S. Sarkar, A. K. Sinha, M. Pradhan, M. Basu, Y. Negishi, T. Pal
J. Phys. Chem. C, 115, 1659-1673 (2011).
2010
66)"Thermodynamic and Kinetics Aspects of Spherical MnO2 Nanoparticle
Synthesis in Isoamyl Alcohol: An Ex Situ Study for Particles to One-Dimensional
Shape Transformation"
A. K. Sinha, M. Basu, M. Pradhan, S. Sarkar, Y. Negishi, T. Pal
J. Phys. Chem. C, 114, 21173-21183 (2010).
65)"An Aminolytic Approach Towards Hierarchical β-Ni(OH)2 Nanoporous
Architectures: A Bimodal Forum for Photocatalytic and Surface Enhanced
Raman Scattering (SERS) Activity"
S. Sarkar, M. Pradhan, A. K. Sinha, M. Basu, Y. Negishi, T. Pal
Inorg. Chem., 49, 8813-8827 (2010).
64)"Evolution of Hierarchical Hexagonal Stacked Plates of CuS from
Liquid-Liquid Interface and its Photocatalytic Application for Oxidative
Degradation of Different Dyes under Indoor Lighting"
M. Basu, A. K. Sinha, M. Pradhan, S. Sarkar, Y. Negishi, G. Gupta, T.
Pal
Environ. Sci. Technol., 44, 6313-6318 (2010).
63)"Continous Mudulation of Electronic Structure of Stable Thiolate-Protected
Au25 Cluster by Ag Doping"
Y. Negishi, T. Iwai, M. Ide
Chem. Commun., 46, 4713-4715 (2010).
62)"Isolation, Structure, and Stability of A Dodecanethiolate-Protected
Pd1Au24 Cluster"
Y. Negishi, W. Kurashige, Y. Niihori, T. Iwasa, K. Nobusada
Phys. Chem. Chem. Phys., 12, 6219-6225 (2010).
Invited Article as "a Winner of PCCP Prize"
61)"Hierarchical Superparamagnetic Magnetite Nanowafers from Resin
Bound [Fe(bpy)3]2+ Matrix”
M. Basu, A. K. Sinha, S. Sarkar, M. Pradhan, S. M. Yusuf, Y. Negishi,
T. Pal
Langmuir, 26, 5836-5842 (2010).
60)"Fluorescent Fe(II) Metallo-Supermolecular Polymers: Metal-Ion
Self-Assembly of New Bis-Terpyridine Containing Triethylene Glycol Chains”
M. Higuchi, R. Pal, Y. Negishi, T. Tsukuda, D. Kurth
Polym. J., 42, 336-341 (2010).
94)"Layer-by-Layer Deposition of Silver/Gold Nanoparticles for Catalytic
Reduction of Nitroaromatics”
S. Jana, S. Pande, A. K. Sinha, S. Sarkar, M. Pradhan, M. Basu, Y. Negishi,
A. Anjali, T. Pal
J. Nanosci. Nanotechnol., 10, 847-859 (2010).
2009
58)"Size Determination of Gold Clusters by Polyacrylamide Gel Electrophoresis
in a Large Cluster Region”
K. Kimura, N. Sugimoto, S. Sato, H. Yao, Y. Negishi, T.Tsukuda
J. Phys. Chem. C, 113, 14076-14082 (2009).
2008
57)"Luminescence Properties of Metallo-Supramolecular Coordination
Polymers Assembled From Pyridine Ring Functionalized Ditopic Bis-Terpyridines
and Ru(II) Ion”
F. S. Han, M. Higuchi, T. Ikeda, Y. Negishi, T. Tsukuda, D. G. Kurth
J. Mater. Chem., 18, 4555-4560 (2008).
56)"Ubiquitous 8 and 29 kDa Gold:Alkanethiolate Cluster Compounds:
Mass Spectrometric Determination of Molecular Formulas and Structural Implications”
N. K. Chaki, Y. Negishi, H. Tsunoyama, Y. Shichibu, T. Tsukuda
J. Am. Chem. Soc.(communications), 130, 8608-8610 (2008)
55) "Electronic Structure of Dendrimer-Au Hybrid Nanoparticles: Hard X-ray Photoemission Study"
Y. Murase, T. Kitagawa, M. Imamura, A. Tanaka, H. Yasuda, Y. Negishi,
T. Tsukuda, S. Ueda, Y. Yamashita, H. Yoshikawa, K. Kobayashi
Trans. MRS-J, 33, 169−172 (2008).
2007
54)"Origin of Magic Stability of Thiolated Gold Clusters: A Case Study
on Au25(SC6H13)18”
Y. Negishi, N. K. Chaki, Y. Shichibu, R. L. Whetten, T. Tsukuda
J. Am. Chem. Soc.(communications), 129, 11322-11323 (2007)．
53)"Thiolate-Induced Structural Reconstruction of Gold Clusters Probed
by 197Au Mössbauer Spectroscopy"
K. Ikeda, Y. Kobayashi, Y. Negishi, M. Seto, T. Iwasa, K. Nobusada, T.
Tsukuda, N. Kojima
J. Am. Chem. Soc.(communications), 129, 7230-7231 (2007).
52)"Electronic Structures of Dendrimer-Encapsulated Au Nanoclusters"
M. Imamura, T. Miyashita, A. Tanaka, H. Yasuda, Y. Negishi, T. Tsukuda
Eur. Phys. J. D, 43, 233-236 (2007).
51)"Biicosahedral Gold Clusters [Au25(PPh3)10(SCnH2n+1)5Cl2]2+ (n=2-18):
a Stepping Stone to Cluster-Assembled Materials"
Y. Shichibu, Y. Negishi, T. Watanabe, N. K. Chaki, H. Kawaguchi, T. Tsukuda
J. Phys. Chem. C (Letters), 111, 7845-7847 (2007).
50)"Effect of Ag-Doping on the Catalytic Activity of Polymer-Stabilized
Au Clusters in Aerobic Oxidation of Alcohol"
N. K. Chaki, H. Tsunoyama, Y. Negishi, H. Sakurai, T. Tsukuda
J. Phys. Chem. C (Letters), 111, 4885-4888 (2007).
49)“Extremely High Stability of Glutathionate-Protected Au25 Clusters against
Core Etching”
Y. Shichibu, Y. Negishi, H. Tsunoyama, M. Kanehara, T. Teranishi, T. Tsukuda
Small (communications), 3, 835-839 (2007).
48)“Formation of Alkanethiolate-Protected Gold Clusters with Unprecedented
Core Sizes in the Thiolation of Polymer-Stabilized Gold Clusters”
H. Tsunoyama, P. Nickut, Y. Negishi, K. Al-Shamery, Y. Matsumoto, and
T. Tsukuda
J. Phys. Chem. C, 111, 4153-4158 (2007).
2006
47)“X-Ray Magnetic Circular Dichroism of Size-Selected, Thiolated Gold
Clusters”
Y. Negishi, H. Tsunoyama, M. Suzuki, N. Kawamura, M. M. Matsushita, K.
Maruyama, T. Sugawara, T. Yokoyama, T. Tsukuda
J. Am. Chem. Soc.(communications), 128, 12034-12035 (2006).
46)“Kinetic Stabilization of Growing Gold Clusters by Passivation with
Thiolates”
Y. Negishi, Y. Takasugi, S. Sato, H. Yao, K. Kimura, T. Tsukuda
J. Phys. Chem. B (Letters), 110, 12218-12221 (2006).
45)“Chiroptical Activity of BINAP-Stabilized Undecagold Clusters”
Y. Yanagimoto, Y. Negishi, H. Fujihara, and T. Tsukuda
J. Phys. Chem. B (Letters), 110, 11611-11614 (2006).
44)“Chromatographic Isolation of “Missing” Au55 Clusters Protected by Alkanethiolates”
H. Tsunoyama, Y. Negishi, T. Tsukuda
J. Am. Chem. Soc.(communications), 128, 6036-6037 (2006).
43)“Electron Localization in Negatively Charged Formamide Clusters Studied
by Photodetachement Spectroscopy”
T. Maeyama, Y. Negishi, T. Tsukuda, I. Yagi, N. Mikami
Phys. Chem. Chem. Phys., 7, 827-833 (2006).
Selected as "Outside Front Cover"
42) "Spectroscopic Investigation of Dendrimer-Encapsulated Gold Clusters"
M. Imamura, T. Miyashita, A. Tanaka, H. Yasuda, Y. Yanagimoto, Y. Negishi, T. Tsukuda
Trans. MRS-J, 31, 517−521 (2006).
2005
41)“Subnanometer-Sized Gold Clusters with Dual Molecular Receptors: Synthesis
and Assembly in One-dimensional Arrangements”
Y. Negishi, H. Tsunoyama, Y. Yanagimoto, T. Tsukuda
Chem. Lett., 34, 1638-1639 (2005).
40)“Large-Scale Synthesis of Thiolated Au25 Clusters via Ligand Exchange
Reactions of Phosphine-Stabilized Au11 Clusters”
Y. Shichibu, Y. Negishi, T. Tsukuda, T. Teranishi
J. Am. Chem. Soc.(communications), 127, 13464-13465 (2005).
39)“Size-Specific Catalytic Activity of Polymer-Stabilized Gold Nanoclusters
for Aerobic Alcohol Oxidation in Water”
H. Tsunoyama, H. Sakurai, Y. Negishi, T. Tsukuda
J. Am. Chem. Soc.(communications), 127, 9374-9375 (2005).
38)“Glutathione-Protected Gold Clusters Revisited: Bridging the Gap between
Gold(I)-Thiolate Complexes and Thiolate-Protected Gold Nanocrystals”
Y. Negishi, K. Nobusada, T. Tsukuda
J. Am. Chem. Soc., 127, 5261-5270 (2005).
2004
37)“Colloidal Gold Nanoparticles as Catalyst for Carbon-Carbon Bond Formation:
Application to Aerobic Homocoupling of Phenylboronic Acid in Water”
H. Tsunoyama, H. Sakurai, N. Ichikuni, Y. Negishi, T. Tsukuda
Langmuir(Letters), 20, 11293-11296 (2004).
36)“Magic-Numbered Aun Clusters Protected by Glutathione Monolayers (n
= 18, 21, 25, 28, 32, 39): Isolation and Spectroscopic Characterization”
Y. Negishi, Y. Takasugi, S. Sato, H. Yao, K. Kimura, T. Tsukuda
J. Am. Chem. Soc.(communications), 126, 6518-6519 (2004).
35)“Structures and Stabilities of Alkanethiolate Monolayers on Palladium
Clusters as Studied by Gel Permeation Chromatography”
H. Murayama, T. Narushima, Y. Negishi, T. Tsukuda
J. Phys. Chem. B, 108, 3496-3503 (2004).
34)“Highly Oxygenated Fullerene Anions C60On- Formed by Corona Discharge
Ionization in the Gas Phase”
H. Tanaka, K. Takeuchi, Y. Negishi, T. Tsukuda
Chem. Phys. Lett., 384, 283-287 (2004).
33)“Visible Photoluminescence from Nearly Monodispersed Au12 Clusters Protected
by meso-2,3-Dimercaptosuccinic Acid”
Y. Negishi, T. Tsukuda
Chem. Phys. Lett., 383, 161-165 (2004).
2003
32)“EXAFS Study on Interfacial Structure between Pd Cluster and n-Octadecanethiolate
Monolayer: Formation of Mixed Pd-S Interlayer”
H. Murayama, N. Ichikuni, Y. Negishi, T. Nagata, T. Tsukuda
Chem. Phys. Lett., 376, 26-32 (2003).
31)“Self-Assembly of Si Clusters into Single Crystal Arrangements: Formation
of Si10 Cluster Crystals”
S. Sato, N. Yamamoto, K. Nakanishi, H. Yao, K. Kimura, Y. Negishi, T.
Tsukuda
Jpn. J. Appl. Phys., 42, 616-618 (2003).
30)“One-Pot Preparation of Subnanometer-Sized Gold Clusters via Reduction
and Stabilization by meso-2,3-Dimercaptosuccinic Acid”
Y. Negishi T. Tsukuda
J. Am. Chem. Soc.(communications), 125, 4046-4047 (2003).
2002
29)“Formation of Pdn(SR)m Clusters (n<60) in the Reaction of PdCl2 and
RSH (R=n-C18H37, n-C12H25)”
Y. Negishi, H. Murayama, T. Tsukuda
Chem. Phys. Lett., 366, 561-566 (2002).
28)“Structural Evolution in (CO2)n Clusters (n<103) as Studied by Mass
Spectrometry”
Y. Negishi, T. Nagata, T. Tsukuda
Chem. Phys. Lett., 364, 127-132 (2002).
27) "Palladium Clusters Stabilized by Cyclodextrins Catalyze Suzuki-Miyaura
Coupling Reactions in Water"
H. Sakurai, T. Hirao, Y. Negishi, H. Tsunakawa, T. Tsukuda
Trans. MRS-J, 27, 185−188 (2002).
26)”Electronic Structures of HonC60 Clusters (n=1-5): High Electron Acceptability
of C60”
S. Nagao, Y. Negishi, A. Kato, Y. Nakamura, A. Nakajima, K. Kaya
J. Chem. Phys., 117, 3169-3173 (2002).
25)”Behavior of Silicon and Germanium Clusters on C60 Fullerene”
M. Ohara, Y. Nakamura, Y. Negishi, K. Miyajima, A. Nakajima, K. Kaya
J. Phys. Chem. A, 106, 4498-4501 (2002).
2001
24)”Photoelectron Spectroscopy of Vx(Coronene)y and Tix(Coronene)y Anions”
M. A. Duncan, A. M. Knight, Y. Negishi, S. Nagao, K. Judai, A. Nakajima,
K. Kaya
J. Phys. Chem. A, 105, 10093-10097 (2001).
23)”Photoelectron Spectroscopy of Gold-Silver Alloy Cluster Anions”
Y. Negishi, Y. Nakamura, A. Nakajima, K. Kaya
J. Chem. Phys., 115, 3657-3663 (2001).
22)”Electronic Properties of Substituted Aluminum Clusters by Boron and
Carbon Atoms (AlnBm-/AlnCm-); New Insights into s-p Hybridization and Perturbed
Shell Structures”
H. Kawamata, Y. Negishi, A. Nakajima, K. Kaya
Chem. Phys. Lett., 337, 255-262 (2001).
21)“Electronic and Geometric Properties of Exohedral Sodium- and Gold-Fullerenes”
B. Palpant, Y.Negishi, M. Sanekata, K. Miyajima, S. Nagao, K. Judai, D. M. Rayner, B. Simard, P. A. Hackett, A. Nakajima, K. Kaya
J. Chem. Phys., 114, 8459-8466 (2001).
20)“Photoelectron Spectroscopy of Scandium-Arene Complex Anions”
K. Judai, Y. Nakamura, M. Tachibana, Y. Negishi, A. Nakajima, K. Kaya
Chem. Lett., 2, 114-115 (2001).
2000
19)“Visible Photoluminescence of the Deposited Germanium-Oxide Prepared
from Clusters in the Gas Phase”
Y. Negishi, S. Nagao, Y. Nakamura, S. Kamei, A. Nakajima, K. Kaya
J. Appl. Phys., 88, 6037-6043 (2000).
18)“Photoelectron Spectroscopy of Copper Cyanide Cluster Anions: On the
Possibility of Linear and Ring Structures”
Y. Negishi, T. Yasuike, F. Hayakawa, M. Kizawa, S. Yabushita, A. Nakajima, K. Kaya
J. Chem. Phys., 113, 1725-1731 (2000).
17)“Photoelectron Spectroscopy of Tin and Lead Cluster Anions; Application
of Halogen Doping Method”
Y. Negishi, H. Kawamata, F. Hayakawa, A. Nakajima, K. Kaya
J. Electron Spectrosc. Relat. Phenom., 106, 117-126 (2000).
Invited Article to "Special Issue"
16) "Electronic State of Germanium-Oxide Clusters and Their Visible
Emission"
Y. Negishi, S. Nagao, Y. Nakamura, S. Kamei, A. Nakajima, K. Kaya
Trans. MRS-J, 25, 999−1002 (2000).
15) "Electronic and Geometric Structures of Metal-Silicide Clusters"
M. Sanekata, T. Koya, S. Nagao, Y. Negishi, A. Nakajima, K. Kaya
Trans. MRS-J, 25, 1003−1006 (2000).
1999
14)“Photoelectron Spectroscopy of 7-Azaindole-Water Cluster Anions”
A. Nakajima, Y. Negishi, R. Hasumi, K. Kaya
Eur. J. Phys. D, 9, 303-307 (1999).
13)“Generation and Electronic Properties of Lanthanide Cyclooctatetraene
Organometallic Clusters in Gas Phase”
T. Kurikawa, Y. Negishi, F. Hayakawa, S. Nagao, K. Miyajima, A. Nakajima, K. Kaya
Eur. J. Phys. D, 9, 283-287 (1999).
12)“Pyramidal Structures of Lanthanide-C60 Clusters (Lnn(C60)m; Ln=Eu and
Ho)”
S. Nagao, Y. Negishi, A. Kato, Y. Nakamura, A. Nakajima, K. Kaya
J. Phys. Chem. A (Letters), 103, 8909-8914 (1999).
11)“Photoelectron Spectroscopy of Sodium-Covered C60 and C70 Clusters”
B. Palpant, A. Otake, F. Hayakawa, Y. Negishi, A. Nakajima, K. Kaya
Phys. Rev. B, 60, 4509-4512 (1999).
10)“Production of Jet-Cooled Coronene and Coronene Cluster Anions and Their
Study with Photoelectron Spectroscopy”
M. A. Duncan, A. M. Knight, Y. Negishi, S. Nagao, Y. Nakamura, A. Kato, A. Nakajima, K. Kaya
Chem. Phys. Lett., 309, 49-54 (1999).
9)“Photoelectron Spectra of Small Nanophase W Metal Cluster Anions”
G. H. Lee, S. H. Huh, Y. C. Park, F. Hayakawa, Y. Negishi, A. Nakajima,
K. Kaya
Chem. Phys. Lett., 299, 309-314 (1999).
1998
8)“Multiple-Decker Sandwich Complexes of Lanthanide-1,3,5,7 Cyclooctatetraene
[Lnn(C8H8)m] (Ln=Ce, Nd, Eu, Ho, and Yb); Localized Ionic Bonding Structure”
T. Kurikawa, Y. Negishi, F. Hayakawa, S. Nagao, K. Miyajima, A. Nakajima,
K. Kaya
J. Am. Chem. Soc., 120, 11766-11772 (1998).
7)“The Infrared HOMO-LUMO Gap of Germanium Clusters”
Y. Negishi, H. Kawamata, F. Hayakawa, A. Nakajima, K. Kaya
Chem. Phys. Lett., 294, 370-376 (1998).
6)“Geometric and Electronic Structure of Fluorine Bound Silicon Clusters”
R. Kishi, Y. Negishi, H. Kawamata, S. Iwata, A. Nakajima, K. Kaya
J. Chem. Phys., 108, 8039-8058 (1998).
1997
5)“Geometric and Electronic Structures of Silicon-Sodium Binary Clusters.
II. Photoelectron Spectroscopy of SinNam- Cluster Anions”
R. Kishi, H. Kawamata, Y. Negishi, S. Iwata, A. Nakajima, K. Kaya
J. Chem. Phys., 107, 10029-10043 (1997).
4)“Photoelectron Spectroscopy of Transition Metal-Sulfur Cluster Anions”
A. Nakajima, H. Kawamata, T. Hayase, Y. Negishi, K. Kaya
Z. Phys. D, 40, 17-21 (1997).
3)“Photoelectron Spectroscopy of Silicon- and Germanium-Fluorine Binary
Cluster Anions (SinFm-,GenFm-)”
K. Kaya, H. Kawamata, Y. Negishi, T. Hayase, R. Kishi, A. Nakajima
Z. Phys. D, 40, 5-9 (1997).
2)“Photoelectron Spectroscopy of Germanium-Fluorine Binary Cluster Anions:
the HOMO-LUMO Gap Estimation of Gen Clusters”
Y. Negishi, H. Kawamata, T. Hayase, M. Gomei, R. Kishi, F. Hayakawa, A. Nakajima, K. Kaya
Chem. Phys. Lett., 269, 199-207 (1997).
1996
1)“Photoelectron Spectroscopy of Silicon-Fluorine Cluster Anions (SinFm-)”
H. Kawamata, Y. Negishi, R. Kishi, S. Iwata, A. Nakajima, K. Kaya
J. Chem. Phys., 105, 5369-5376 (1996).
